Anisotropic hat-like carbon nanoparticles with tunable inner hollow architectures by growth and dissolution kinetics control.

The synthesis of nanoparticles with a hollow and anisotropic structure have attracted considerable interest in synthetic methodology and diverse potential applications, but endowing them with delicate control of the hollow structure and outer anisotropic morphology remains a significant challenge. In this study, anisotropic nanoparticles with hat-like morphology are prepared via a kinetics-controlled growth and dissolution strategy. Starting from forming solid polymer nanospheres with location-specific compositional chemistry distribution based on the distinct reactivity and growth kinetics of two reactants. After etching by acetone, the inhomogeneity nanospheres transformed to hat-like nanoparticles through the kinetics-controlled dissolution of two kinds of precursors. Due to chemical etching and repolymerization reactions occurring within a single nanospheres, an autonomous asymmetrical repolymerization and concave process are observed, which is novel at the nanoscale. Moreover, regulating the amount of ammonia significantly impacts the growth kinetics of precursors, primarily affecting the composition and subsequent dissolution process of solid polymer nanospheres, which play an important role in constructing polymer nanoparticles with varying morphologies and internal structures. The as-synthesized hat-like carbon nanoparticles with an open carbon structure, highly porous shell, and favorable N-doped functionalities demonstrate a potential candidate for lithium-sulfur batteries.