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利用便携式近红外光谱技术与化学计量学联用对姜粉进行快速质量评价和产地识别。

Rapid quality evaluation and geographical origin recognition of ginger powder by portable NIRS in tandem with chemometrics.

机构信息

College of Food Science and Nutritional Engineering, China Agricultural University, Beijing 100083, China; Sanya Institute of China Agricultural University, Hainan 572025, China; Institute of Healthy Food Industry, China Agricultural University, Jiangsu 225721, China.

Institute of Healthy Food Industry, China Agricultural University, Jiangsu 225721, China; Food Detection and Supervision Center, Xinghua, Jiangsu 225721, China.

出版信息

Food Chem. 2024 Apr 16;438:137931. doi: 10.1016/j.foodchem.2023.137931. Epub 2023 Nov 8.

Abstract

Ginger powder is an important spice that is susceptible to improper sales such as adulteration or geographical fraud. In this study, a portable near infrared spectroscopy was used to quantitatively predict the 6-gingerol content, an important quality index of ginger, as well as to identify the gingers from three origins in China. Specifically, the optimal preprocessing method was first investigated by comparing the predictions of models. Then three feature variable selection methods including PCA, CARS, and RFrog, on the quantitative analysis of 6-gingerol were also compared, respectively. After comparison, the PLS model established on the S-G combined with SNV preprocessing outperformed the others. The PLS regression of 6-gingerol with variables selected by RFrog possessed the R of 0.9463, R of 0.9497, and the RPD of 4.2257, respectively. Moreover, the results further verified that the LDA model by SPA variables extraction successfully identify gingers from different origins with 100 % accuracy.

摘要

姜粉是一种重要的香料,容易出现掺假或产地欺诈等不正当销售行为。在这项研究中,我们使用便携式近红外光谱法定量预测姜的重要质量指标——6-姜酚的含量,同时鉴别来自中国三个产地的姜。具体而言,我们通过比较模型的预测结果,首先研究了最佳预处理方法。然后,我们分别比较了三种特征变量选择方法(主成分分析、竞争自适应重加权采样和随机蛙跳)在 6-姜酚定量分析中的应用。比较后发现,基于 S-G 结合 SNV 预处理的 PLS 模型表现优于其他模型。通过随机蛙跳选择变量建立的 6-姜酚 PLS 回归模型的 R²为 0.9463,RPD 为 4.2257。此外,结果还进一步验证了 SPA 变量提取的 LDA 模型能够成功识别来自不同产地的姜,准确率为 100%。

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