Bubble Engineering on Micro-/Nanostructured Electrodes for Water Splitting.

Bubble behaviors play crucial roles in mass transfer and energy efficiency in gas evolution reactions. Combining multiscale structures and surface chemical compositions, micro-/nanostructured electrodes have drawn increasing attention. With the aim to identify the exciting opportunities and rationalize the electrode designs, in this review, we present our current comprehension of bubble engineering on micro-/nanostructured electrodes, focusing on water splitting. We first provide a brief introduction of gas wettability on micro-/nanostructured electrodes. Then we discuss the advantages of micro-/nanostructured electrodes for mass transfer (detailing the lowered overpotential, promoted supply of electrolyte, and faster bubble growth kinetics), localized electric field intensity, and electrode stability. Following that, we outline strategies for promoting bubble detachment and directional transportation. Finally, we offer our perspectives on this emerging field for future research directions.