College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, No. 30, South Puzhu Road, Nanjing 211816, China; State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, No. 30, South Puzhu Road, Nanjing 211816, China.
School of Pharmaceutical Sciences, Nanjing Tech University, No. 30, South Puzhu Road, Nanjing 211816, China.
Food Chem. 2024 Apr 16;438:138031. doi: 10.1016/j.foodchem.2023.138031. Epub 2023 Nov 17.
In this study, Polycaprolactone (PCL)/Yam Polysaccharide (YP) fiber membranes loaded the ultrasound-mediated assembly of 2-Hydroxypropyl-β-cyclodextrin (HP-β-CD)/Epicatechin gallate (ECG) inclusion complexes were prepared by electrospinning technology for food packaging. Morphology, infrared spectroscopy and X-ray diffraction results showed that the inclusion complexes were successfully assembled. With the addition of inclusion complexes, the average diameter of the fibers increased from 2480.96 to 10179.12 nm, the crystallinity decreased, the thermal stability improved, the hydrophilicity enhanced, and the water vapor permeability enhanced. Meanwhile, thermogravimetry and differential scanning calorimetry results showed that the inclusion complexes formed hydrogen bonds between the fibers, which improved the thermal stability, but the mechanical behavior suffered a certain loss. In addition, the fiber membrane could continuously release ECG within 240 h, which showed excellent antibacterial effects both in vitro and in vivo. These results indicated that the fiber film developed based on electrospinning had a broad application prospect in food packaging.
本研究采用静电纺丝技术制备了负载超声介导组装 2-羟丙基-β-环糊精(HP-β-CD)/表儿茶素没食子酸酯(ECG)包合物的聚己内酯(PCL)/山芋多糖(YP)纤维膜,用于食品包装。形态学、红外光谱和 X 射线衍射结果表明包合物成功组装。随着包合物的加入,纤维的平均直径从 2480.96 纳米增加到 10179.12 纳米,结晶度降低,热稳定性提高,亲水性增强,水蒸气透过率提高。同时,热重分析和差示扫描量热分析结果表明,包合物在纤维之间形成氢键,提高了热稳定性,但力学性能受到一定损失。此外,纤维膜在 240 小时内可持续释放 ECG,体外和体内均表现出优异的抗菌效果。这些结果表明,基于静电纺丝技术开发的纤维膜在食品包装方面具有广阔的应用前景。