Cao Saizheng, Xu Chenchao, Fukui Hiroshi, Manjo Taishun, Dong Ying, Shi Ming, Liu Yang, Cao Chao, Song Yu
Center for Correlated Matter and School of Physics, Zhejiang University, 310058, Hangzhou, China.
School of Physics, Hangzhou Normal University, 310036, Hangzhou, China.
Nat Commun. 2023 Nov 23;14(1):7671. doi: 10.1038/s41467-023-43454-1.
Owing to its unique geometry, the kagome lattice hosts various many-body quantum states including frustrated magnetism, superconductivity, and charge-density waves (CDWs). In this work, using inelastic X-ray scattering, we discover a dynamic short-range [Formula: see text] CDW that is dominant in the kagome metal ScVSn above T ≈ 91 K, competing with the [Formula: see text] CDW that orders below T. The competing CDW instabilities lead to an unusual CDW formation process, with the most pronounced phonon softening and the static CDW occurring at different wavevectors. First-principles calculations indicate that the [Formula: see text] CDW is energetically favored, while a wavevector-dependent electron-phonon coupling (EPC) promotes the [Formula: see text] CDW as the ground state, and leads to enhanced electron scattering above T. These findings underscore EPC-driven correlated many-body physics in ScVSn and motivate studies of emergent quantum phases in the strong EPC regime.
由于其独特的几何结构, Kagome晶格包含各种多体量子态,包括受挫磁性、超导性和电荷密度波(CDW)。在这项工作中,我们使用非弹性X射线散射,发现在Kagome金属ScVSn中,高于T≈91 K时,一种动态短程[公式:见正文] CDW占主导地位,与低于T时有序的[公式:见正文] CDW相互竞争。相互竞争的CDW不稳定性导致了一个不寻常的CDW形成过程,最明显的声子软化和静态CDW出现在不同的波矢处。第一性原理计算表明,[公式:见正文] CDW在能量上更有利,而波矢依赖的电子-声子耦合(EPC)促进了[公式:见正文] CDW作为基态,并导致高于T时电子散射增强。这些发现强调了ScVSn中EPC驱动的相关多体物理,并激发了对强EPC regime中涌现量子相的研究。