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探索结冷胶在提高石油采收率方面的潜力。

Exploring Potential of Gellan Gum for Enhanced Oil Recovery.

作者信息

Gussenov Iskander, Berzhanova Ramza Zh, Mukasheva Togzhan D, Tatykhanova Gulnur S, Imanbayev Bakyt A, Sagyndikov Marat S, Kudaibergenov Sarkyt E

机构信息

Institute of Polymer Materials and Technology, microdistrict "Atyrau 1", 3/1, Almaty 050019, Kazakhstan.

Petroleum Engineering Department, Satbayev University, Satbayev str. 22a, Almaty 050043, Kazakhstan.

出版信息

Gels. 2023 Oct 29;9(11):858. doi: 10.3390/gels9110858.

DOI:10.3390/gels9110858
PMID:37998948
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10671067/
Abstract

Extensive laboratory and field tests have shown that the gelation response of gellan gum to saline water makes it a promising candidate for enhanced oil recovery (EOR). The objective of this mini-review is to evaluate the applicability of gellan gum in EOR and compare its efficiency to other precursors, in particular, hydrolyzed polyacrylamide (HPAM). At first, the "sol-gel" phase transitions of gellan gum in aqueous-salt solutions containing mono- and divalent cations are considered. Then the rheological and mechanical properties of gellan in diluted aqueous solutions and gel state are outlined. The main attention is paid to laboratory core flooding and field pilot tests. The plugging behavior of gellan in laboratory conditions due to "sol-gel" phase transition is discussed in the context of conformance control and water shut-off. Due to its higher strength, gellan gum gel provided ~6 times greater resistance to the flow of brine in a 1 mm-width fracture compared to HPAM gel. The field trials carried out in the injection and production wells of the Kumkol oilfield, situated in Kazakhstan, demonstrated that over 6 and 11 months, there was an incremental oil recovery of 3790 and 5890 tons, respectively. To put it into perspective, using 1 kg of dry gellan resulted in the incremental production of 3.52 m (or 22 bbls) of oil. The treatment of the production well with 1 wt.% gellan solution resulted in a considerable decrease in the water cut up to 10-20% without affecting the oil flow rate. The advantages and disadvantages of gellan compared to HPAM are analyzed together with the economic feasibility of gellan over HPAM. The potential for establishing gellan production in Kazakhstan is emphasized. It is anticipated that gellan gum, manufactured through fermentation using glucose-fructose syrup from Zharkent and Burunday corn starch plants, could be expanded in the future for applications in both the food industry and oil recovery.

摘要

大量的实验室和现场测试表明，结冷胶对盐水的胶凝反应使其成为提高石油采收率（EOR）的一个有前景的候选材料。本综述的目的是评估结冷胶在提高石油采收率中的适用性，并将其效率与其他前驱体，特别是水解聚丙烯酰胺（HPAM）进行比较。首先，考虑结冷胶在含有单价和二价阳离子的盐水溶液中的“溶胶-凝胶”相变。然后概述了结冷胶在稀水溶液和凝胶状态下的流变学和力学性能。主要关注实验室岩心驱替和现场先导试验。在调剖和堵水的背景下，讨论了结冷胶在实验室条件下由于“溶胶-凝胶”相变而产生的封堵行为。由于其更高的强度，与HPAM凝胶相比，结冷胶凝胶在1毫米宽的裂缝中对盐水流动的阻力大6倍左右。在哈萨克斯坦的库姆科尔油田的注入井和生产井中进行的现场试验表明，在6个月和11个月的时间里，分别增产原油3790吨和5890吨。从另一个角度来看，使用1千克干结冷胶可增产3.52立方米（或22桶）原油。用1 wt.%的结冷胶溶液处理生产井，可使含水率大幅降低至1%至20%，而不影响油流速度。分析了结冷胶与HPAM相比的优缺点，以及结冷胶相对于HPAM的经济可行性。强调了在哈萨克斯坦建立结冷胶生产的潜力。预计通过使用扎尔肯特和布伦代玉米淀粉厂的葡萄糖-果糖糖浆发酵生产的结冷胶，未来可能会扩大其在食品工业和石油采收中的应用。

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