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基于激光制备的金属有机框架衍生的Cu-CuO@C复合电化学传感器同时检测儿茶酚和对苯二酚

Simultaneous Catechol and Hydroquinone Detection with Laser Fabricated MOF-Derived Cu-CuO@C Composite Electrochemical Sensor.

作者信息

Levshakova Aleksandra, Kaneva Maria, Borisov Evgenii, Panov Maxim, Shmalko Alexandr, Nedelko Nikolai, Mereshchenko Andrey S, Skripkin Mikhail, Manshina Alina, Khairullina Evgeniia

机构信息

Institute of Chemistry, St. Petersburg State University, St. Petersburg 199034, Russia.

Ioffe Institute, St. Petersburg 194021, Russia.

出版信息

Materials (Basel). 2023 Nov 18;16(22):7225. doi: 10.3390/ma16227225.

DOI:10.3390/ma16227225
PMID:38005154
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10673110/
Abstract

The conversion of metal-organic frameworks (MOFs) into advanced functional materials offers a promising route for producing unique nanomaterials. MOF-derived systems have the potential to overcome the drawbacks of MOFs, such as low electrical conductivity and poor structural stability, which have hindered their real-world applications in certain cases. In this study, laser scribing was used for pyrolysis of a Cu-based MOF ([Cu{1,4-CH(COO)}(4,4'-bipy)]) to synthesize a Cu-CuO@C composite on the surface of a screen-printed electrode (SPE). Scanning electron microscopy, X-ray diffractometry, and Energy-dispersive X-ray spectroscopy were used for the investigation of the morphology and composition of the fabricated electrodes. The electrochemical properties of Cu-CuO@C/SPE were studied by cyclic voltammetry and differential pulse voltammetry. The proposed flexible electrochemical Cu-CuO@C/SPE sensor for the simultaneous detection of hydroquinone and catechol exhibited good sensitivity, broad linear range (1-500 μM), and low limits of detection (0.39 μM for HQ and 0.056 μM for CT).

摘要

将金属有机框架（MOF）转化为先进功能材料为制备独特的纳米材料提供了一条有前景的途径。源自MOF的体系有潜力克服MOF的缺点，比如低电导率和较差的结构稳定性，在某些情况下这些缺点阻碍了它们的实际应用。在本研究中，采用激光划刻对铜基金属有机框架（[Cu{1,4-CH(COO)}(4,4'-bipy)]）进行热解，以在丝网印刷电极（SPE）表面合成Cu-CuO@C复合材料。利用扫描电子显微镜、X射线衍射仪和能量色散X射线光谱仪对制备电极的形貌和组成进行研究。通过循环伏安法和差分脉冲伏安法研究了Cu-CuO@C/SPE的电化学性能。所提出的用于同时检测对苯二酚和邻苯二酚的柔性电化学Cu-CuO@C/SPE传感器表现出良好的灵敏度、宽线性范围（1-500μM）以及低检测限（对HQ为0.39μM，对CT为0.056μM）。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b932/10673110/3f2c6da971ea/materials-16-07225-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b932/10673110/d36d89652360/materials-16-07225-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b932/10673110/8ddf2a88311b/materials-16-07225-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b932/10673110/e666b1976b91/materials-16-07225-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b932/10673110/e9e02b1f6a51/materials-16-07225-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b932/10673110/d980b4333b52/materials-16-07225-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b932/10673110/3f2c6da971ea/materials-16-07225-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b932/10673110/d36d89652360/materials-16-07225-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b932/10673110/8ddf2a88311b/materials-16-07225-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b932/10673110/e666b1976b91/materials-16-07225-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b932/10673110/e9e02b1f6a51/materials-16-07225-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b932/10673110/d980b4333b52/materials-16-07225-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b932/10673110/3f2c6da971ea/materials-16-07225-g005.jpg

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2
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Sensors (Basel). 2023 Aug 5;23(15):6957. doi: 10.3390/s23156957.
3
镍/钨酸/碳化钨复合纳米片作为用于光电化学过氧化氢传感和析氢的高效催化剂。
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