Key Laboratory of Environment and Health, Ministry of Education & Ministry of Environmental Protection, and State Key Laboratory of Environmental Health (Incubating), School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, Wuhan, 430030, China.
School of Medicine, Henan University of Chinese Medicine, Zhengzhou, 450046, China.
Environ Sci Pollut Res Int. 2024 Jan;31(1):280-292. doi: 10.1007/s11356-023-31212-1. Epub 2023 Nov 28.
In this study, source water, finished water, and tap water were sampled monthly from two large drinking water treatment plants in Wuhan city, China for 12 months where physicochemical and microbiological parameters were measured, and the complex monitoring data was analyzed using single-factor assessment method, entropy weight water quality index (EWQI), and multivariate statistical techniques (i.e., cluster analysis (CA), discriminant analysis, and correlation analysis). The results of the single-factor assessment method showed that the total nitrogen pollution was the main problem in the source water quality, and the finished and tap water met the required quality standards. The EWQI values indicated that the overall quality of the source, finished, and tap water samples was "Excellent." In addition, strengthening monitoring of parameters with high entropy weights, including Pb, Hg, sulfide, Cr in surface water and Hg, aerobic bateria count, and As in drinking water, were suggested, as they were prone to drastic changes. Spatial CA grouped the finished and tap water samples from the same plant into a cluster. Temporal CA grouped 12 sampling times of source water into Cluster 1 (June), Cluster 2 (April-May, and July-November), and Cluster 3 (December-March). Concerning finished and tap water, except the October was regrouped, the result of temporal CA was consistent to that of the source water. Based on similar characteristics of water samples, monitoring sites and frequency can be optimized. Moreover, stepwise discriminant analysis indicated that the spatiotemporal variations in water quality among CA-groups were enough to be explained by four or five parameters, which provided a basis for the selection of monitoring parameters. The results of correlation analysis showed that few pairwise correlations were both significant (P < 0.05) and stable across sampling sites, suggesting that the number of monitoring parameters was difficult to reduce through substitution. In summary, this study illustrates the usefulness of EWQI and the multivariate statistical techniques in the water quality assessment and monitoring strategy optimization.
在这项研究中,从中国武汉市的两个大型饮用水处理厂每月采集原水、成品水和自来水样本,共 12 个月,测量理化和微生物参数,并使用单因素评价法、熵权水质指数(EWQI)和多元统计技术(即聚类分析(CA)、判别分析和相关分析)对复杂的监测数据进行分析。单因素评价方法的结果表明,总氮污染是原水水质的主要问题,而成品水和自来水符合所需的质量标准。EWQI 值表明,原水、成品水和自来水样品的整体质量为“优秀”。此外,建议加强对高熵权重参数的监测,包括地表水的 Pb、Hg、硫化物、Cr 和饮用水中的 Hg、需氧菌计数和 As,因为这些参数容易发生剧烈变化。空间 CA 将来自同一工厂的成品水和自来水样本分为一组。时间 CA 将 12 个原水采样时间分为 Cluster 1(6 月)、Cluster 2(4 月-5 月和 7 月-11 月)和 Cluster 3(12 月-3 月)。就成品水和自来水而言,除了 10 月被重新分组外,时间 CA 的结果与原水的结果一致。根据水样的相似特征,可以优化监测站点和频率。此外,逐步判别分析表明,CA 组之间水质的时空变化足以用四个或五个参数来解释,这为监测参数的选择提供了依据。相关分析的结果表明,很少有两两相关在统计学上是显著的(P<0.05),并且在采样点之间是稳定的,这表明通过替代来减少监测参数的数量是困难的。总之,本研究说明了 EWQI 和多元统计技术在水质评估和监测策略优化中的有用性。