Schardt Jan, Gerken Martina
Opt Express. 2023 Oct 23;31(22):36136-36149. doi: 10.1364/OE.499349.
Optoelectronic devices based on organic semiconductor materials are on the rise for sensing applications due to their integrability with a variety of substrates - including flexible substrates for wearables. For sensing applications often narrowband absorption is desired with suppression of light at other wavelengths. Here, we investigate narrowband absorption enhancement of organic photodetectors (OPD) with an integrated lateral nanostructure. We show with finite-element simulations, that resonant excitation of low absorbing wavelength regimes allow for up to 3 times the absolute absorption at wavelengths on resonance compared to wavelengths off resonance. We present experimental results for CuPc/C OPDs fabricated on grating nanostructures with periods of 350 nm and 400 nm and a grating depth of 140 nm as well as a grating period of 370 nm and grating depths of 30 nm. Angle-resolved transmission spectra clearly show the optical resonance effects. In order to evaluate the electrical resonance effects a measurement system is introduced based on angular laser excitation. An angular resolution of 0.1° is achieved in the analysis of the OPD photocurrent response. Using the measurement setup an increase of the photocurrent by up to 50% is observed for the TE-resonance. It is demonstrated that the resonance wavelength is tuned simply by adjusting the grating period without changes in the layer thicknesses. This opens up new opportunities in realizing pixels of different wavelength response next to each other employing a single active stack design.
基于有机半导体材料的光电器件因能与多种衬底(包括可穿戴设备的柔性衬底)集成,在传感应用中日益兴起。对于传感应用,通常希望实现窄带吸收并抑制其他波长的光。在此,我们研究了具有集成横向纳米结构的有机光电探测器(OPD)的窄带吸收增强情况。我们通过有限元模拟表明,低吸收波长区域的共振激发使得共振波长处的绝对吸收相比非共振波长提高了3倍。我们展示了在周期为350 nm和400 nm、光栅深度为140 nm以及周期为370 nm、光栅深度为30 nm的光栅纳米结构上制备的CuPc/C OPD的实验结果。角分辨透射光谱清楚地显示了光学共振效应。为了评估电共振效应,引入了基于角激光激发的测量系统。在分析OPD光电流响应时实现了0.1°的角分辨率。使用该测量装置,观察到TE共振时光电流增加了50%。结果表明,只需调整光栅周期就能调谐共振波长,而无需改变层厚度。这为采用单一有源堆叠设计实现相邻的不同波长响应像素开辟了新机遇。