Ullah Qasim, Khan Salman Ahmad, Arifuddin Mohammed, Mohsin Md, Kausar Samrin, Fatema Nahid, Ahmer Mohammad Faraz
Chemistry Section, School of Sciences, Maulana Azad National Urdu University, Gachibowli, Hyderabad, 500032, India.
Chemistry Department, Directorate of Distance Education (DDE), Maulana Azad National Urdu University, Gachibowli, Hyderabad, 500032, India.
J Fluoresc. 2025 Jan;35(1):543-557. doi: 10.1007/s10895-023-03514-7. Epub 2023 Dec 22.
This review basically concerned with the application of different Schiff bases (SB) based fluorimetric (turn-off and turn-on) and colorimetric chemosensors for the detection of heavy metal cations particularly Al(III), Fe(III), and Cr(III) ions. Chemosensors based on Schiff bases have exhibited outstanding performance in the detection of different metal cations due to their facile and in-expensive synthesis, and their excellent coordination ability with almost all metal cations and stabilize them in different oxidation states. Moreover, Schiff bases have also been used as antifungal, anticancer, analgesic, anti-inflammatory, antibacterial, antiviral, antioxidant, and antimalarial etc. The Schiff base also can be used as an intermediate for the formation of various heterocyclic compounds. In this review, we have focused on the research work performed on the development of chemosensors (colorimetric and fluorometric) for rapid detection of trivalent metal cations particularly Al(III), Fe(III), and Cr(III) ions using Schiff base as a ligand during 2020-2022.
本综述主要涉及不同席夫碱(SB)基荧光(猝灭和开启)和比色化学传感器在检测重金属阳离子特别是铝(III)、铁(III)和铬(III)离子方面的应用。基于席夫碱的化学传感器由于其合成简便、成本低廉,以及与几乎所有金属阳离子具有出色的配位能力并能在不同氧化态下使其稳定,在检测不同金属阳离子方面表现出优异的性能。此外,席夫碱还被用作抗真菌、抗癌、止痛、抗炎、抗菌、抗病毒、抗氧化和抗疟疾等药物。席夫碱还可作为形成各种杂环化合物的中间体。在本综述中,我们重点关注了2020年至2022年期间以席夫碱为配体用于快速检测三价金属阳离子特别是铝(III)、铁(III)和铬(III)离子的化学传感器(比色和荧光)的研发工作。