• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

一种基于蒽的荧光探针，用于在水介质中选择性灵敏地检测铬（III）离子及其实际应用。

An anthracene based fluorescent probe for the selective and sensitive detection of Chromium (III) ions in an aqueous medium and its practical application.

作者信息

KarakuŞ Erman

机构信息

Organic Chemistry Laboratory, Chemistry Group, National Metrology Institute, (TÜBİTAK UME), Scientific and Technological Research Council of Turkey, Kocaeli Turkey.

出版信息

Turk J Chem. 2020 Aug 18;44(4):941-949. doi: 10.3906/kim-2003-41. eCollection 2020.

DOI:10.3906/kim-2003-41
PMID:33488204
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7751903/
Abstract

An anthracene based fluorescent probe, integrated with thiophene moiety, exhibited selective and sensitive detection of chromium (III) ions over other metal ions. Its synthesis was achieved by simple mixing of two commercially available compounds, 2-aminoanthracene, and 2-thiophenecarboxaldehyde, in onestep without the needed complex purification process. The probe molecule ( ) offered exceptional features such as "turn-on" fluorescence response, low detection limit (0.4 μM), and fast response time (<1 min) via C=N bond hydrolysis. Also, a simple test paper system was developed for the rapid detection of chromium (III) ions with the naked eye.

摘要

一种基于蒽并与噻吩部分相结合的荧光探针，对铬（III）离子表现出相对于其他金属离子的选择性和灵敏检测。其合成通过将两种市售化合物2-氨基蒽和2-噻吩甲醛简单混合一步完成，无需复杂的纯化过程。该探针分子通过C=N键水解呈现出“开启”荧光响应、低检测限（0.4 μM）和快速响应时间（<1分钟）等优异特性。此外，还开发了一种简单的试纸系统用于肉眼快速检测铬（III）离子。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/7de9887a888a/turkjchem-44-941-fig004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/1430912229b0/turkjchem-44-941-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/acba9a56eb2a/turkjchem-44-941-fig001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/53a471b2ab1c/turkjchem-44-941-fig002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/ec21c5c0f36a/turkjchem-44-941-fig003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/63a40aaec01d/turkjchem-44-941-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/7de9887a888a/turkjchem-44-941-fig004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/1430912229b0/turkjchem-44-941-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/acba9a56eb2a/turkjchem-44-941-fig001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/53a471b2ab1c/turkjchem-44-941-fig002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/ec21c5c0f36a/turkjchem-44-941-fig003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/63a40aaec01d/turkjchem-44-941-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/7de9887a888a/turkjchem-44-941-fig004.jpg

相似文献

1
An anthracene based fluorescent probe for the selective and sensitive detection of Chromium (III) ions in an aqueous medium and its practical application.一种基于蒽的荧光探针，用于在水介质中选择性灵敏地检测铬（III）离子及其实际应用。
Turk J Chem. 2020 Aug 18;44(4):941-949. doi: 10.3906/kim-2003-41. eCollection 2020.
2
An Anthracene and Indole-based Fluorescent Probe for the Detection of Chromium(III) Ions in Real Water Samples.一种用于检测实际水样中铬（III）离子的基于蒽和吲哚的荧光探针。
J Fluoresc. 2023 Jan;33(1):185-190. doi: 10.1007/s10895-022-03041-x. Epub 2022 Nov 2.
3
A Phenalenone-based Fluorescent Probe for the Detection of Fe ions.一种用于检测铁离子的苯并菲酮基荧光探针。
J Fluoresc. 2023 Mar;33(2):707-712. doi: 10.1007/s10895-022-03117-8. Epub 2022 Dec 12.
4
Highly Selective Turn-On Fluorescent Chemodosimeter for Al Detection through Al -Promoted Hydrolysis of C=N Double Bonds in the 8-Hydroxyquinoline Aldehyde Schiff Base.通过8-羟基喹啉醛席夫碱中碳氮双键的铝促进水解实现对铝的高选择性开启型荧光化学传感器
Chemistry. 2017 Apr 11;23(21):5081-5089. doi: 10.1002/chem.201606024. Epub 2017 Mar 23.
5
Dual Fluorophore Containing Efficient Photoinduced Electron Transfer Based Molecular Probe for Selective Detection of Cr and PO Ions through Fluorescence " Turn-On-Off" Response in Partial Aqueous and Biological Medium: Live Cell Imaging and Logic Application.双荧光团高效光诱导电子转移分子探针选择性检测 Cr 和 PO 离子：部分水相和生物介质中的荧光“开启-关闭”响应、活细胞成像和逻辑应用。
Anal Chem. 2018 Sep 18;90(18):10974-10981. doi: 10.1021/acs.analchem.8b02570. Epub 2018 Aug 27.
6
Highly Selective Detection of Cr Ion with Colorimetric & Fluorescent Response Via Chemodosimetric Approach in Aqueous Medium.通过化学计量法在水介质中对Cr离子进行比色和荧光响应的高选择性检测。
J Fluoresc. 2018 Mar;28(2):663-670. doi: 10.1007/s10895-018-2228-1. Epub 2018 Apr 14.
7
Nitrogen-doped carbon dot threads as a "turn-off" fluorescent probe for permanganate ions and its hydrogel hybrid as a naked eye sensor for gold(III) ions.氮掺杂碳点纤维作为过锰酸根离子的“关闭”型荧光探针及其水凝胶杂化体作为金(III)离子的裸眼传感器。
Anal Bioanal Chem. 2020 May;412(12):2993-3003. doi: 10.1007/s00216-020-02550-7. Epub 2020 Mar 7.
8
A rhodamine-triazole fluorescent chemodosimeter for Cu detection and its application in bioimaging.一种用于检测铜的罗丹明-三唑荧光化学传感器及其在生物成像中的应用。
Luminescence. 2018 Feb;33(1):64-70. doi: 10.1002/bio.3373. Epub 2017 Jul 17.
9
Naked-eye Detection of Hg in Practical Applications Using a Highly Selective and Sensitive Fluorescent Probe.使用高选择性和灵敏荧光探针在实际应用中对汞进行裸眼检测。
Anal Sci. 2018 Dec 10;34(12):1411-1417. doi: 10.2116/analsci.18P274. Epub 2018 Sep 7.
10
Anthracene-Based Highly Selective and Sensitive Fluorescent "" Chemodosimeter for Hg.基于蒽的高选择性和高灵敏度汞荧光“化学计量器”
ACS Omega. 2018 Oct 31;3(10):12341-12348. doi: 10.1021/acsomega.8b01142. Epub 2018 Oct 1.

引用本文的文献

1
The investigation of fluorescence and metal interaction properties of racemic 7,8,9,10-tetrahydro-3-hydroxy-4-(1-hydroxyethyl)benzo[c]chromen-6-one.外消旋7,8,9,10-四氢-3-羟基-4-(1-羟乙基)苯并[c]色烯-6-酮的荧光和金属相互作用性质研究
Turk J Chem. 2021 Aug 18;46(2):295-301. doi: 10.3906/kim-2106-6. eCollection 2022.
2
Recent Developments in Colorimetric and Fluorometric Detection Methods of Trivalent Metal Cations (Al, Fe and Cr) Using Schiff Base Probes: At a Glance.使用席夫碱探针的三价金属阳离子（铝、铁和铬）比色和荧光检测方法的最新进展：概述
J Fluoresc. 2025 Jan;35(1):543-557. doi: 10.1007/s10895-023-03514-7. Epub 2023 Dec 22.
3

本文引用的文献

1
Synthetic ratiometric fluorescent probes for detection of ions.用于离子检测的合成比率荧光探针。
Chem Soc Rev. 2020 Jan 2;49(1):143-179. doi: 10.1039/c9cs00243j.
2
Highly selective fluorescence 'turn off' sensing of picric acid and efficient cell labelling by water-soluble luminescent anthracene-bridged poly(N-vinyl pyrrolidone).水溶性发光蒽桥联聚（N-乙烯基吡咯烷酮）对苦味酸的高选择性荧光“猝灭”传感及高效细胞标记
Analyst. 2019 May 28;144(11):3620-3634. doi: 10.1039/c8an02417k.
3
Anthracene-Based Highly Selective and Sensitive Fluorescent "" Chemodosimeter for Hg.
A Phenalenone-based Fluorescent Probe for the Detection of Fe ions.
一种用于检测铁离子的苯并菲酮基荧光探针。
J Fluoresc. 2023 Mar;33(2):707-712. doi: 10.1007/s10895-022-03117-8. Epub 2022 Dec 12.
4
Thiophene-Appended Benzothiazole Compounds for Ratiometric Detection of Copper and Cadmium Ions with Comparative Density Functional Theory Studies and Their Application in Real-Time Samples.用于铜离子和镉离子比率检测的噻吩基苯并噻唑化合物及比较密度泛函理论研究及其在实际样品中的应用
ACS Omega. 2022 Nov 2;7(45):41361-41369. doi: 10.1021/acsomega.2c05157. eCollection 2022 Nov 15.
5
A Comprehensive Review on Thiophene Based Chemosensors.噻吩基化学传感器的综合评述
J Fluoresc. 2022 Jan;32(1):19-56. doi: 10.1007/s10895-021-02833-x. Epub 2021 Oct 8.
基于蒽的高选择性和高灵敏度汞荧光“化学计量器”
ACS Omega. 2018 Oct 31;3(10):12341-12348. doi: 10.1021/acsomega.8b01142. Epub 2018 Oct 1.
4
Highly Selective Detection of Cr Ion with Colorimetric & Fluorescent Response Via Chemodosimetric Approach in Aqueous Medium.通过化学计量法在水介质中对Cr离子进行比色和荧光响应的高选择性检测。
J Fluoresc. 2018 Mar;28(2):663-670. doi: 10.1007/s10895-018-2228-1. Epub 2018 Apr 14.
5
Fluorescent chemosensors: the past, present and future.荧光化学传感器：过去、现在和未来。
Chem Soc Rev. 2017 Dec 7;46(23):7105-7123. doi: 10.1039/c7cs00240h. Epub 2017 Oct 11.
6
Chromium(III) and iron(III) inhibits replication of DNA and RNA viruses.铬（III）和铁（III）抑制DNA和RNA病毒的复制。
Biometals. 2017 Aug;30(4):565-574. doi: 10.1007/s10534-017-0027-9. Epub 2017 Jun 13.
7
Anthracene excimer-based "turn on" fluorescent sensor for Cr(3+) and Fe(3+) ions: Its application to living cells.基于蒽准分子的用于Cr(3+)和Fe(3+)离子的“开启”型荧光传感器：其在活细胞中的应用。
Talanta. 2016 Sep 1;158:63-69. doi: 10.1016/j.talanta.2016.05.017. Epub 2016 May 19.
8
Fluorescent, MRI, and colorimetric chemical sensors for the first-row d-block metal ions.用于第一过渡金属 d 区金属离子的荧光、磁共振成像和比色化学传感器。
Chem Soc Rev. 2015 Jul 7;44(13):4337-66. doi: 10.1039/c4cs00285g. Epub 2014 Nov 12.
9
Small molecule-based ratiometric fluorescence probes for cations, anions, and biomolecules.用于阳离子、阴离子和生物分子的基于小分子的比率荧光探针。
Chem Soc Rev. 2015 Jul 7;44(13):4185-91. doi: 10.1039/c4cs00280f. Epub 2014 Oct 6.
10
Nutrients other than carbohydrates: their effects on glucose homeostasis in humans.除碳水化合物以外的营养素：它们对人体葡萄糖内稳态的影响。
Diabetes Metab Res Rev. 2015 Jan;31(1):14-35. doi: 10.1002/dmrr.2533.