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一种基于蒽的荧光探针,用于在水介质中选择性灵敏地检测铬(III)离子及其实际应用。

An anthracene based fluorescent probe for the selective and sensitive detection of Chromium (III) ions in an aqueous medium and its practical application.

作者信息

KarakuŞ Erman

机构信息

Organic Chemistry Laboratory, Chemistry Group, National Metrology Institute, (TÜBİTAK UME), Scientific and Technological Research Council of Turkey, Kocaeli Turkey.

出版信息

Turk J Chem. 2020 Aug 18;44(4):941-949. doi: 10.3906/kim-2003-41. eCollection 2020.

Abstract

An anthracene based fluorescent probe, integrated with thiophene moiety, exhibited selective and sensitive detection of chromium (III) ions over other metal ions. Its synthesis was achieved by simple mixing of two commercially available compounds, 2-aminoanthracene, and 2-thiophenecarboxaldehyde, in onestep without the needed complex purification process. The probe molecule ( ) offered exceptional features such as "turn-on" fluorescence response, low detection limit (0.4 μM), and fast response time (<1 min) via C=N bond hydrolysis. Also, a simple test paper system was developed for the rapid detection of chromium (III) ions with the naked eye.

摘要

一种基于蒽并与噻吩部分相结合的荧光探针,对铬(III)离子表现出相对于其他金属离子的选择性和灵敏检测。其合成通过将两种市售化合物2-氨基蒽和2-噻吩甲醛简单混合一步完成,无需复杂的纯化过程。该探针分子通过C=N键水解呈现出“开启”荧光响应、低检测限(0.4 μM)和快速响应时间(<1分钟)等优异特性。此外,还开发了一种简单的试纸系统用于肉眼快速检测铬(III)离子。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a4/7751903/1430912229b0/turkjchem-44-941-sch001.jpg

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