Colombo Elena, Casadei Delio, Baricci Andrea, Casalegno Andrea
Politecnico di Milano, Department of Energy, Via Lambruschini 4, Milano 20156, Italy.
HardwareX. 2023 Nov 27;16:e00495. doi: 10.1016/j.ohx.2023.e00495. eCollection 2023 Dec.
The design of an open zero-gradient hardware is proposed in this work. The hardware is thought for characterizing single Polymer Electrolyte Membrane Fuel Cells (PEMFCs), specifically Membrane Electrode Assemblies (MEAs), with a focus on transport application. The objective of the proposed design is to minimize both operation and degradation heterogeneities over the cell active area in order to evaluate material properties only. It is indeed specifically intended to quantify the PEMFC materials performance without accounting for any interdependency between the layers of the MEA and the cell hardware design (e.g. heating/cooling system and flow field features). This is granted by combining high stoichiometry ratios of the gas reactants and limited pressure drops: they indeed keep uniform operating conditions (concentration in the gas phase, relative humidity, pressure and temperature), as verified by the electrochemical and operational characterization. With such characteristics, accurate information about both the performance and the degradation of the MEA materials can be provided. This tool is powerful for assessing the ranking in terms of performance and durability of different PEMFCs, as well as for application in the field of the materials local diagnostics.
本文提出了一种开放式零梯度硬件的设计方案。该硬件旨在用于表征单个聚合物电解质膜燃料电池(PEMFC),特别是膜电极组件(MEA),重点是传输应用。所提出设计的目标是最小化电池活性区域上的操作和降解不均匀性,以便仅评估材料特性。它确实专门用于量化PEMFC材料的性能,而不考虑MEA各层与电池硬件设计之间的任何相互依赖性(例如加热/冷却系统和流场特征)。这是通过结合高化学计量比的气体反应物和有限的压降来实现的:它们确实保持了均匀的操作条件(气相中的浓度、相对湿度、压力和温度),这已通过电化学和操作表征得到验证。具有这些特性,可以提供有关MEA材料性能和降解的准确信息。该工具对于评估不同PEMFC在性能和耐久性方面的排名以及在材料局部诊断领域的应用非常强大。