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用于环境相关应用的良性设计植物提取物介导的氧化铜纳米颗粒的制备

Benign-by-design plant extract-mediated preparation of copper oxide nanoparticles for environmentally related applications.

作者信息

Ahmad Awais, Khan Mariam, Osman Sameh M, Haassan Ahmad M, Javed Muhammad Hassan, Ahmad Anees, Rauf Abdul, Luque Rafael

机构信息

Departamento de Quimica Organica, Universidad de Cordoba, Edificio Marie Curie (C-3), Ctra Nnal IV-A, Km 396, E14104, Cordoba, Spain.

School of Applied Sciences and Humanity (NUSASH), National University of Technology, Islamabad, 44000, Pakistan.

出版信息

Environ Res. 2024 Apr 15;247:118048. doi: 10.1016/j.envres.2023.118048. Epub 2023 Dec 30.

Abstract

A facile, cost-competitive, scalable and novel synthetic approach is used to prepare copper oxide (CuO) nanoparticles (NPs) using Betel leaf (Piper betle) extracts as reducing, capping, and stabilizing agents. CuO-NPs were characterized using various analytical techniques, including Fourier-transform infrared (FTIR) spectroscopy, ultraviolet-visible (UV-Vis) spectroscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), as well as photoluminescence (PL) measurements. The activity of CuO-NPs was investigated towards Congo red dye degradation, supercapacitor energy storage and antibacterial activity. A maximum of 89% photodegradation of Congo red dye (CR) was obtained. The nanoparticle modified electrode also exhibited a specific capacitance (C) of 179 Fg. Furthermore, the antibacterial potential of CuO NPs was evaluated against Bacillus subtilis and Pseudomonas aeruginosa, both strains displaying high antibacterial performance.

摘要

采用一种简便、成本竞争力强、可扩展且新颖的合成方法,以槟榔叶(蒌叶)提取物作为还原剂、封端剂和稳定剂来制备氧化铜(CuO)纳米颗粒(NPs)。使用各种分析技术对CuO-NPs进行了表征,包括傅里叶变换红外(FTIR)光谱、紫外可见(UV-Vis)光谱、扫描电子显微镜(SEM)、X射线衍射(XRD)、高分辨率透射电子显微镜(HRTEM)以及光致发光(PL)测量。研究了CuO-NPs对刚果红染料降解、超级电容器能量存储和抗菌活性的性能。刚果红染料(CR)的最大光降解率达到了89%。纳米颗粒修饰电极还表现出179 F/g的比电容(C)。此外,评估了CuO NPs对枯草芽孢杆菌和铜绿假单胞菌的抗菌潜力,两种菌株均显示出较高的抗菌性能。

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