Yao Yunping, Yuan Huiping, Chen Chen, Liang Jia, Li Changmo
State Key Laboratory of Food Nutrition and Safety, Key Laboratory of Food Nutrition and Safety, Ministry of Education, College of Food Science and Engineering, Tianjin University of Science and Technology, Tianjin 300457, China.
Foods. 2023 Dec 20;13(1):29. doi: 10.3390/foods13010029.
Resveratrol (3,5,4'-trihydroxystilbene), a naturally occurring polyphenol that is widely utilized in functional food due to its antioxidant, anti-inflammatory, anti-cancer and anti-aging properties. In the present study, the antioxidant capacity and oxidation products of resveratrol in soybean oil were investigated. The antioxidant activity of resveratrol was evaluated by employing various in vitro antioxidant assays such as DPPH scavenging activities, ferric reducing abilities (FRAP) and oxygen radical absorbance capacity (ORAC). Furthermore, monitoring the peroxide value and the acid value of soybean oil with the addition of 200-1000 μg/g of resveratrol at 60 and 180 °C. It was found that when the concentration of resveratrol in soybean oil was 600 µg/g, the antioxidant capacity was most effective. Resveratrol and its thermal degradation products were identified using liquid chromatography-mass spectrometry (LC-MS) and gas chromatography-mass spectrometry (GC-MS). There were seven nonvolatile oxidation products with mass-to-charge ratios of 138.03, 171.04, 185.10, 157.03, 436.13, 244.07 and 306.09 kg/C and two volatile oxidation products with mass-to-charge ratios of 100.05 and 158.13 kg/C were identified. The research findings may provide essential information for the development of resveratrol as functional oils in future.
白藜芦醇(3,5,4'-三羟基茋)是一种天然存在的多酚,因其具有抗氧化、抗炎、抗癌和抗衰老特性而被广泛应用于功能性食品中。在本研究中,对白藜芦醇在大豆油中的抗氧化能力和氧化产物进行了研究。通过采用各种体外抗氧化试验,如DPPH清除活性、铁还原能力(FRAP)和氧自由基吸收能力(ORAC)来评估白藜芦醇的抗氧化活性。此外,在60℃和180℃下,监测添加200 - 1000μg/g白藜芦醇的大豆油的过氧化值和酸值。结果发现,当大豆油中白藜芦醇的浓度为600μg/g时,抗氧化能力最为有效。使用液相色谱 - 质谱联用仪(LC - MS)和气相色谱 - 质谱联用仪(GC - MS)对白藜芦醇及其热降解产物进行了鉴定。鉴定出七种质荷比为138.03、171.04、185.10、157.03、436.13、244.07和306.09 kg/C的非挥发性氧化产物以及两种质荷比为100.05和158.13 kg/C的挥发性氧化产物。该研究结果可能为未来将白藜芦醇开发为功能性油脂提供重要信息。