AGH University of Krakow, Mickiewicza 30 Av. 30-059, Krakow, Poland.
Bioresour Technol. 2024 Feb;394:130290. doi: 10.1016/j.biortech.2023.130290. Epub 2024 Jan 11.
The presented research results the gasification process of biomass waste (brewery spend grain, wheat straw, hay, pine sawdust). Experimental investigations focused on determining the influence of gasification agent (CO, steam, and steam and CO mixture) and the presence of a solid catalyst (MgO∙CaO, TiO, CuO and SrO). Investigations were performed towards syngas production. A wide range of analyses and instrumental methods were used to determine the properties of gasification process products, including: GC, TGA, FTIR, SEM, BET. The main component of syngas obtained produced in atmosphere CO and steam mixture was hydrogen. The H concentration increased from 20% up to 44% in case of brewery spend grain. The presence of the catalyst in the gasification process favoured the tar cracking reaction. The amount of tar was reduced by more than 17% in case of brewery spend grain. As well as syngas composition was enriched with CH, H and CO concentration.
本研究介绍了生物质废料(啤酒厂废粮、麦秸、干草、松木屑)的气化过程。实验研究重点确定了气化剂(CO、蒸汽和 CO 与蒸汽的混合物)和固体催化剂(MgO·CaO、TiO、CuO 和 SrO)的存在对气化过程的影响。研究针对合成气的生产进行了开展。使用了广泛的分析和仪器方法来确定气化过程产品的性质,包括:GC、TGA、FTIR、SEM、BET。在 CO 和蒸汽混合物气氛中获得的合成气的主要成分是氢气。在啤酒厂废粮的情况下,H 浓度从 20%增加到 44%。在气化过程中添加催化剂有利于焦油裂化反应。焦油的量减少了 17%以上,啤酒厂废粮的情况也是如此。合成气的组成也富含 CH、H 和 CO 浓度。