Characterization of Methane Extraction during ScCO-ECBM: Consideration of Competitive Adsorption of ScCO and CH.

The supercritical CO enhanced coalbed methane (ScCO-ECBM) technology is still in the development stage, and many simulation experiments and theoretical studies related to ScCO-ECBM are being improved. Previous research works have conducted many studies on the competitive adsorption of CO and CH in coal, but there is less research on the competitive adsorption of ScCO and CH and its impact on methane extraction characteristics. In this study, a permeability model considering the competitive effects of effective stress and adsorption swelling on permeability was established. Based on the assumed conditions and permeability evolution model, different injected pressure and initial methane pressure conditions were set to obtain quantitative results of the competitive adsorption of ScCO and CH, permeability changes, and CH production. By obtaining the competitive adsorption relationship between ScCO and CH, we analyzed the evolution law of permeability and its impact on CH production. It was found that ScCO has a stronger competitive adsorption capacity, and the competitive adsorption capacity of ScCO and CH is more sensitive to injected pressure. Under two different conditions, it was found that the higher the injected pressure or injected differential pressure, the higher the initial permeability. However, due to the greater sensitivity of the competitive adsorption capacity of ScCO and CH to injected pressure, the greater the injected pressure in the later stage, the greater the decrease in permeability, resulting in a situation where the permeability at an injected pressure of 10 MPa is lower than that at an injected pressure of 8 MPa. A simple comparison was made between gaseous CO and ScCO, and it was found that although injecting ScCO has a stronger adsorption swelling capacity that affects permeability changes, its stronger adsorption capacity can effectively displace methane and higher injected pressure, injected temperature, and advantages such as fracturing and extraction that are not yet reflected in the model. This study provides some guidance for numerical simulation of the ScCO-ECBM process and the enhancement of coalbed methane extraction.