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基于芦苇秸秆的生物炭作为介孔吸附剂去除离子染料的合成及效率比较

Synthesis and efficiency comparison of reed straw-based biochar as a mesoporous adsorbent for ionic dyes removal.

作者信息

Tomin Oleksii, Vahala Riku, Yazdani Maryam R

机构信息

Department of Built Environment, School of Engineering, Aalto University, P.O. Box 15200, FI-00076, Aalto, Finland.

Department of Mechanical Engineering, School of Engineering, Aalto University, P.O. Box 14400, FI-00076, Aalto, Finland.

出版信息

Heliyon. 2024 Jan 15;10(2):e24722. doi: 10.1016/j.heliyon.2024.e24722. eCollection 2024 Jan 30.

DOI:10.1016/j.heliyon.2024.e24722
PMID:38298730
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10828687/
Abstract

The reed straw is assessed as a potential source of widely available renewable biomass for biochar production and compared with two other waste-based biomasses, namely fruit stones blend, and brewery spent grains. The biochars were activated via steam and CO. While steam activation yielded 12 % carbon from reed biomass, CO activation resulted in biomass degradation. The characterization of reed biochar showed a mesoporous structure and a high surface area of 514 m/g. The adsorption tests displayed a decent adsorption capacity of biochar, with values of 92.6 mg/g for methylene violet dye and 35.7 mg/g for acid green dye. Only 1 g/L dosage of reed biochar was able to remove 99 % of the 50 mg/L methylene violet solution in 15 min and 60 % of the 50 mg/L acid green solution in 10 min. The obtained results demonstrate reed biomass as a suitable source for biochar production as well as reed-based biochar as a promising dye adsorbent.

摘要

芦苇秸秆被评估为一种具有广泛可用性的可再生生物质来源,可用于生产生物炭,并与其他两种基于废物的生物质进行了比较,即果核混合物和啤酒糟。生物炭通过蒸汽和一氧化碳进行活化。虽然蒸汽活化从芦苇生物质中产生了12%的碳,但一氧化碳活化导致生物质降解。芦苇生物炭的表征显示出介孔结构和514 m²/g的高比表面积。吸附测试表明生物炭具有良好的吸附能力,亚甲基紫染料的吸附值为92.6 mg/g,酸性绿染料的吸附值为35.7 mg/g。仅1 g/L剂量的芦苇生物炭就能在15分钟内去除50 mg/L亚甲基紫溶液的99%,在10分钟内去除50 mg/L酸性绿溶液的60%。所得结果表明芦苇生物质是生产生物炭的合适来源,基于芦苇的生物炭是一种有前景的染料吸附剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ee33/10828687/32c66248ac28/ga1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ee33/10828687/32c66248ac28/ga1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ee33/10828687/32c66248ac28/ga1.jpg

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