Pu Ying, Wu Gaoying, Wang Yue, Wu Xiaobing, Chu Na, Zeng Raymond Jianxiong, Jiang Yong
Fujian Provincial Key Laboratory of Soil Environmental Health and Regulation, College of Resources and Environment, Fujian Agriculture and Forestry University, Fuzhou 350002, China.
Fujian Provincial Key Laboratory of Soil Environmental Health and Regulation, College of Resources and Environment, Fujian Agriculture and Forestry University, Fuzhou 350002, China; CAS Key Laboratory of Environmental and Applied Microbiology, Environmental Microbiology Key Laboratory of Sichuan Province, Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041, China; University of Chinese Academy of Sciences, Beijing 100049, China.
Sci Total Environ. 2024 Mar 25;918:170758. doi: 10.1016/j.scitotenv.2024.170758. Epub 2024 Feb 6.
Electrochemical CO reduction (CORR), fueled by clean and renewable energy, presents a promising method for utilizing CO effectively. The electrocatalytic reduction of CO to CO using a gas diffusion electrode (GDE) has shown great potential for industrial applications due to its high reaction rate and selectivity. However, guaranteeing its long-term stability still poses a significant challenge. In this study, we conducted a comprehensive investigation into various strategies to enhance the stability of the GDE. These strategies involved modifying the structure of the substrate, such as the gas diffusion layer (GDL) and the back side of the GDL (macroporous layer side). Additionally, we explored modifications to the catalyst layer (CL) and the front of the CL. To address these stability concerns, we proposed a practical approach that involved surface coating using carbon black in combination with in situ cyclic voltammetry (CV) cycles on Ag/Ag/polytetrafluoroethylene (PTFE). The partial Faradaic efficiency exceeded 80 % within a span of 70 h. Electron microscopy and electrochemical characterization revealed that the implementation of in situ CV led to a reduction in catalyst particle size and the formation of a porous surface structure. By enhancing the stability of the GDE, this research opens up possibilities for the advancement of hybrid systems that focus on the production and utilization of syngas.
由清洁可再生能源驱动的电化学CO还原(CORR)为有效利用CO提供了一种很有前景的方法。使用气体扩散电极(GDE)将CO电催化还原为CO,因其高反应速率和选择性,在工业应用中显示出巨大潜力。然而,保证其长期稳定性仍然是一个重大挑战。在本研究中,我们对提高GDE稳定性的各种策略进行了全面研究。这些策略包括改变基底结构,如气体扩散层(GDL)及其背面(大孔层一侧)。此外,我们还探索了对催化剂层(CL)及其正面的改性。为了解决这些稳定性问题,我们提出了一种实用方法,即在Ag/Ag/聚四氟乙烯(PTFE)上使用炭黑进行表面涂层并结合原位循环伏安法(CV)循环。在70小时内,部分法拉第效率超过了80%。电子显微镜和电化学表征表明,原位CV的实施导致催化剂粒径减小并形成多孔表面结构。通过提高GDE的稳定性,本研究为推进专注于合成气生产和利用的混合系统开辟了可能性。