Takeuchi Kazuma, Ogura Hiroyuki, Hasuike Noriyuki, Kamikawa Takeshi
Corporate R&D Group, Keihanna Research Center, Kyocera Corporation, 3-5-3 Hikaridai, Seika-cho, Soraku-gun, Kyoto, Japan.
Faculty of Electrical Engineering and Electronics, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto, 606-8585, Japan.
Sci Rep. 2024 Feb 9;14(1):3330. doi: 10.1038/s41598-024-53478-2.
Strain engineering for gallium nitride has been studied by many researchers to improve the performance of various devices (i.e., light-emitting diodes, laser diodes, power devices, high electron mobility transistors, and so on). Further miniaturization of gallium nitride devices will clearly continue in the future, and therefore an accurate understanding of the strain state in the devices is essential. However, a measurement technique for axially resolved evaluation of the strain in microareas has not yet been established. In this study, we revealed that the anisotropic strain state induced in c-plane growth gallium nitride is linked to the split state of Raman peaks, which were measured with [Formula: see text] and [Formula: see text] polarized configurations. The anisotropic strain state in c-plane gallium nitride was induced in the 3D-structure by epitaxial lateral overgrowth, which enabled successful performance of our work. This result allowed us to axially decompose the strain in c-plane gallium nitride through Raman spectroscopy and establish a measurement technique for axially resolving the strain. This measurement technique is feasible using a conventional Raman spectrometer. Furthermore, the method was indicated to be applicable to all wurtzite-type crystals, including gallium nitride, silicon carbide, and aluminum nitride. Our work provides a new perspective for understanding the complex strain state in microareas for wurtzite materials. Comprehending the strain state, which strongly affects device performance, will help promote the research and development of III-V semiconductor devices.
许多研究人员对氮化镓的应变工程进行了研究,以提高各种器件(即发光二极管、激光二极管、功率器件、高电子迁移率晶体管等)的性能。氮化镓器件在未来显然会继续进一步小型化,因此准确了解器件中的应变状态至关重要。然而,尚未建立用于微区应变轴向分辨评估的测量技术。在本研究中,我们发现,在c面生长的氮化镓中诱导的各向异性应变状态与拉曼峰的分裂状态有关,这些拉曼峰是在[公式:见正文]和[公式:见正文]偏振配置下测量的。通过外延横向生长在三维结构中诱导了c面氮化镓中的各向异性应变状态,这使我们的工作得以成功进行。这一结果使我们能够通过拉曼光谱法轴向分解c面氮化镓中的应变,并建立一种轴向分辨应变的测量技术。使用传统的拉曼光谱仪,这种测量技术是可行的。此外,该方法被证明适用于所有纤锌矿型晶体,包括氮化镓、碳化硅和氮化铝。我们的工作为理解纤锌矿材料微区中的复杂应变状态提供了一个新的视角。了解强烈影响器件性能的应变状态将有助于推动III-V族半导体器件的研发。