Zhong Mian, Li Shichen, Zou Yao, Fan Hongyun, Jiang Yong, Qiu Chao, Luo Jinling, Yang Liang
Institute of Electronic and Electrical Engineering, Civil Aviation Flight University of China, Deyang 618307, China.
School of Mathematics and Physics, Southwest University of Science and Technology, Mianyang 621010, China.
Micromachines (Basel). 2024 Feb 17;15(2):285. doi: 10.3390/mi15020285.
The exceptional performance of graphene has driven the advancement of its preparation techniques and applications. Laser-induced graphene (LIG), as a novel graphene preparation technique, has been applied in various fields. Graphene periodic structures created by the LIG technique exhibit superhydrophobic characteristics and can be used for deicing and anti-icing applications, which are significantly influenced by the laser parameters. The laser surface treatment process was simulated by a finite element software analysis (COMSOL Multiphysics) to optimize the scanning parameter range, and the linear array surface structure was subsequently fabricated by the LIG technique. The generation of graphene was confirmed by Raman spectroscopy and energy-dispersive X-ray spectroscopy. The periodic linear array structure was observed by scanning electron microscopy (SEM) and confocal laser imaging (CLSM). In addition, CLSM testings, contact angle measurements, and delayed icing experiments were systematically performed to investigate the effect of scanning speed on surface hydrophobicity. The results show that high-quality and uniform graphene can be achieved using the laser scanning speed of 125 mm/s. The periodic linear array structures can obviously increase the contact angle and suppress delayed icing. Furthermore, these structures have the enhanced ability of the electric heating deicing, which can reach 100 °C and 240 °C within 15 s and within 60 s under the DC voltage power supply ranging from 3 to 7 V, respectively. These results indicate that the LIG technique can be developed to provide an efficient, economical, and convenient approach for preparing graphene and that the hydrophobic surface array structure based on LIG has considerable potential for deicing and anti-icing applications.
石墨烯的优异性能推动了其制备技术和应用的发展。激光诱导石墨烯(LIG)作为一种新型的石墨烯制备技术,已被应用于各个领域。通过LIG技术制备的石墨烯周期性结构具有超疏水特性,可用于除冰和防冰应用,而这些应用会受到激光参数的显著影响。利用有限元软件分析(COMSOL Multiphysics)对激光表面处理过程进行模拟,以优化扫描参数范围,随后通过LIG技术制备线性阵列表面结构。通过拉曼光谱和能量色散X射线光谱确认了石墨烯的生成。通过扫描电子显微镜(SEM)和共聚焦激光成像(CLSM)观察周期性线性阵列结构。此外,系统地进行了CLSM测试、接触角测量和延迟结冰实验,以研究扫描速度对表面疏水性的影响。结果表明,使用125 mm/s的激光扫描速度可以获得高质量且均匀的石墨烯。周期性线性阵列结构可以显著增加接触角并抑制延迟结冰。此外,这些结构具有增强的电加热除冰能力,在3至7 V的直流电压电源下,分别在15 s内和60 s内可达到100°C和240°C。这些结果表明,可以开发LIG技术以提供一种高效、经济且便捷的石墨烯制备方法,并且基于LIG的疏水表面阵列结构在除冰和防冰应用中具有相当大的潜力。