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质子交换膜燃料电池(PEMFC)复合双极板的研究现状:纳米填料与结构优化

Current status of research on composite bipolar plates for proton exchange membrane fuel cells (PEMFCs): nanofillers and structure optimization.

作者信息

Wenkai Li, Zhiyong Xie, Haodong Zeng

机构信息

Central South University Changsha 410017 Hunan Province China

出版信息

RSC Adv. 2024 Feb 28;14(10):7172-7194. doi: 10.1039/d3ra08054d. eCollection 2024 Feb 21.

Abstract

The proton exchange membrane fuel cell (PEMFC) is an efficient and clean energy source with promising applications. However, drawbacks such as high cost and low durability limit its application. Bipolar plates are an important component of PEMFCs, which not only account for a large proportion of the price and quality, but also affect the performance and durability of PEMFCs. Unlike traditional graphite and metal bipolar plates, composite bipolar plates have the advantages of easy processing, low cost, and corrosion resistance, but their lower performance limits their practical applications. This paper firstly summarizes the current research progress of various nanofillers used to improve the performance of composite bipolar plates, and discusses the improvement of the performance of composite bipolar plates by different forms and types of nanofillers. The morphological characteristics of different types of nanofillers and their effects on the improvement of conductive pathways are also analyzed. Subsequently, the means of structural optimization of composite bipolar plates are summarized, and specific optimization methods for phase interface, graphite/resin dispersion morphology, and conductive network structure are discussed in detail. Finally, challenges are discussed. Overall, this review can provide a reference for future research on composite bipolar plates.

摘要

质子交换膜燃料电池(PEMFC)是一种高效且清洁能源,具有广阔的应用前景。然而,诸如成本高和耐久性低等缺点限制了其应用。双极板是PEMFC的重要组成部分,它不仅在价格和质量中占很大比例,而且还影响PEMFC的性能和耐久性。与传统的石墨和金属双极板不同,复合双极板具有易于加工、成本低和耐腐蚀的优点,但其较低的性能限制了它们的实际应用。本文首先总结了用于提高复合双极板性能的各种纳米填料的当前研究进展,并讨论了不同形式和类型的纳米填料对复合双极板性能的改善。还分析了不同类型纳米填料的形态特征及其对改善导电通路的影响。随后,总结了复合双极板的结构优化方法,并详细讨论了相界面、石墨/树脂分散形态和导电网络结构的具体优化方法。最后,讨论了挑战。总体而言,本综述可为未来复合双极板的研究提供参考。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f865/10900183/10e25ac34597/d3ra08054d-f1.jpg

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