2-(2-叠氮苯基)-3-氧代-3-吲哚 1-氧化物的合成、表征及晶体结构
Synthesis, characterization, and crystal structure of 2-(2-azido-phen-yl)-3-oxo-3-indole 1-oxide.
作者信息
Dhote Pawan, Tothadi Srinu, Ramana Chepuri V
机构信息
Organic Chemistry Division, CSIR-National Chemical Laboratory, Pune, 411008, India.
Analytical and Environmental Sciences Division and Centralized Instrumentation Facility, CSIR-Central Salt and Marine Chemicals Research Institute, Gijubhai Badheka Marg, Bhavnagar, 364002 , India.
出版信息
Acta Crystallogr E Crystallogr Commun. 2024 Feb 20;80(Pt 3):310-313. doi: 10.1107/S2056989024001440. eCollection 2024 Mar 1.
An attempt to explore the reactivity of the nitro group in the presence of gold catalysis in comparison to the azide group yielded intriguing results. Surprisingly, only the nitro group exhibited reactivity, ultimately giving rise to the formation of the title isatogen, CHNO. In the crystal structure, weak C-H⋯O hydrogen bonds and π-π stacking inter-actions link the mol-ecules. The structure exhibits disorder of the mol-ecule.
尝试探究在金催化存在下硝基与叠氮基相比的反应活性，得到了有趣的结果。令人惊讶的是，只有硝基表现出反应活性，最终生成了标题中的异吲哚酮CHNO。在晶体结构中，弱的C-H⋯O氢键和π-π堆积相互作用连接着分子。该结构表现出分子无序。
Zotero 插件