Kar Dilip Kumar, V Praveenkumar, Si Satyabrata, Panigrahi Harekrishna, Mishra Smrutirekha
School of Chemical Technology, Kalinga Institute of Industrial Technology, Bhubaneswar, 751024, Odisha, India.
Institute of Chemical Technology (ICT), Indian Oil Campus (IOC), Bhubaneswar, 751013, Odisha, India.
ACS Omega. 2024 Feb 26;9(10):11050-11080. doi: 10.1021/acsomega.3c07612. eCollection 2024 Mar 12.
Carbon dots (CDs), a novel class of carbon-based nanoparticles, have received a lot of interest recently due to their exceptional mechanical, chemical, and fluorescent properties, as well as their excellent photostability and biocompatibility. CDs' emission properties have already found a variety of potential applications, in which bioimaging and sensing are major highlights. It is widely acknowledged that CDs' fluorescence and surface conditions are closely linked. However, due to the structural complexity of CDs, the specific underlying process of their fluorescence is uncertain and yet to be explained. Because of their low toxicity, robust and wide optical absorption, high chemical stability, rapid transfer characteristics, and ease of modification, CDs have been recognized as promising carbon nanomaterials for a variety of sensing applications. Thus, following such outstanding properties of CDs, they have been mixed and imprinted onto different polymeric components to achieve a highly efficient nanocomposite with improved functional groups and properties. Here, in this review, various approaches and techniques for the preparation of polymer/CDs nanocomposites have been elaborated along with the individual characteristics of CDs. CDs/polymer nanocomposites recently have been highly demanded for sensor applications. The insights from this review are detailed sensor applications of polymer/CDs nanocomposites especially for detection of different chemical and biological analytes such as metal ions, small organic molecules, and several contaminants.
碳点(CDs)是一类新型的碳基纳米颗粒,由于其优异的机械、化学和荧光性能,以及出色的光稳定性和生物相容性,近年来受到了广泛关注。碳点的发光特性已经在多种潜在应用中得到了体现,其中生物成像和传感是主要亮点。人们普遍认为,碳点的荧光与表面状况密切相关。然而,由于碳点结构的复杂性,其荧光产生的具体内在过程尚不确定,有待进一步解释。由于碳点具有低毒性、强而宽的光吸收、高化学稳定性、快速转移特性以及易于修饰等特点,它们已被公认为是用于各种传感应用的有前途的碳纳米材料。因此,基于碳点的这些优异特性,它们已被混合并印迹到不同的聚合物组分上,以获得具有改进官能团和性能的高效纳米复合材料。在此综述中,阐述了制备聚合物/碳点纳米复合材料的各种方法和技术以及碳点的各自特性。近来,碳点/聚合物纳米复合材料在传感器应用中需求很高。本综述的见解详细介绍了聚合物/碳点纳米复合材料在传感器方面的应用,特别是用于检测不同的化学和生物分析物,如金属离子、小有机分子和几种污染物。