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含有焚烧糖渣滤饼和地衣芽孢杆菌 WH 细菌的水泥浆的机械和自修复性能。

Mechanical and self-healing properties of cement paste containing incinerated sugarcane filter cake and Lysinibacillus sp. WH bacteria.

机构信息

Bioscience and Bioinnovation for Sustainability Program, Department of Integrated Science, Faculty of Science, Khon Kaen University, Khon Kaen, 40002, Thailand.

School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima, 30000, Thailand.

出版信息

Sci Rep. 2024 Mar 20;14(1):6716. doi: 10.1038/s41598-024-57492-2.

Abstract

Cement is the most widely used construction material due to its strength and affordability, but its production is energy intensive. Thus, the need to replace cement with widely available waste material such as incinerated black filter cake (IBFC) in order to reduce energy consumption and the associated CO emissions. However, because IBFC is a newly discovered cement replacement material, several parameters affecting the mechanical properties of IBFC-cement composite have not been thoroughly investigated yet. Thus, this work aims to investigate the impact of IBFC as a cement replacement and the addition of the calcifying bacterium Lysinibacillus sp. WH on the mechanical and self-healing properties of IBFC cement pastes. The properties of the IBFC-cement pastes were assessed by determining compressive strength, permeable void, water absorption, cement hydration product, and self-healing property. Increases in IBFC replacement reduced the durability of the cement pastes. The addition of the strain WH to IBFC cement pastes, resulting in biocement, increased the strength of the IBFC-cement composite. A 20% IBFC cement-replacement was determined to be the ideal ratio for producing biocement in this study, with a lower void percentage and water absorption value. Adding strain WH decreases pore sizes, densifies the matrix in ≤ 20% IBFC biocement, and enhances the formation of calcium silicate hydrate (C-S-H) and AFm ettringite phases. Biogenic CaCO and C-S-H significantly increase IBFC composite strength, especially at ≤ 20% IBFC replacement. Moreover, IBFC-cement composites with strain WH exhibit self-healing properties, with bacteria precipitating CaCO crystals to bridge cracks within two weeks. Overall, this work provides an approach to produce a "green/sustainable" cement using biologically enabled self-healing characteristics.

摘要

水泥因其强度和经济性而被广泛应用于建筑,但它的生产是能源密集型的。因此,需要用广泛可用的废物材料代替水泥,例如焚烧后的黑色滤饼(IBFC),以减少能源消耗和相关的 CO 排放。然而,由于 IBFC 是一种新发现的水泥替代材料,一些影响 IBFC-水泥复合材料力学性能的参数尚未得到彻底研究。因此,本工作旨在研究 IBFC 作为水泥替代物的影响,以及添加钙化细菌 Lysinibacillus sp. WH 对 IBFC 水泥砂浆的力学和自修复性能的影响。通过测定抗压强度、可渗透空隙、吸水率、水泥水化产物和自修复性能来评估 IBFC 水泥砂浆的性能。随着 IBFC 替代率的增加,水泥浆体的耐久性降低。向 IBFC 水泥砂浆中添加 WH 菌株,形成生物水泥,会增加 IBFC-水泥复合材料的强度。在这项研究中,确定 20%的 IBFC 水泥替代率是生产生物水泥的理想比例,因为此时的空隙率和吸水率较低。添加 WH 菌株会减小孔径,使在 ≤ 20%IBFC 的生物水泥中基质更加致密,并促进硅酸钙水合物(C-S-H)和 AFm 钙矾石相的形成。生物成因的 CaCO 和 C-S-H 显著提高了 IBFC 复合材料的强度,尤其是在 ≤ 20%IBFC 替代率时。此外,具有 WH 菌株的 IBFC 水泥复合材料具有自修复性能,细菌在两周内沉淀 CaCO 晶体以桥接裂缝。总的来说,这项工作提供了一种使用具有生物功能的自修复特性来生产“绿色/可持续”水泥的方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1b1/11349942/200095959b7b/41598_2024_57492_Fig1_HTML.jpg

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