活性大孔聚合物的3D打印：硫醇-烯化学与聚合诱导相分离
3D printing of reactive macroporous polymers thiol-ene chemistry and polymerization-induced phase separation.
作者信息
Mandsberg Nikolaj K, Aslan Fatma, Dong Zheqin, Levkin Pavel A
机构信息
Karlsruhe Institute of Technology (KIT), Institute of Biological and Chemical Systems - Functional Molecular Systems (IBCS-FMS), Kaiserstrasse 12, Karlsruhe 76131, Germany.
School and Hospital of Stomatology Cheeloo College of Medicine Shandong University & Shandong Key Laboratory of Oral Tissue Regeneration & Shandong Engineering Laboratory for Dental Materials and Oral Tissue Regeneration No. 44-1 Wenhuaxi Road, Jinan, Shandong 250012, China.
出版信息
Chem Commun (Camb). 2024 May 30;60(45):5872-5875. doi: 10.1039/d4cc00466c.
Using thiol-ene chemistry, polymerization-induced phase separation, and DLP 3D printing, we present a method for manufacturing reactive macroporous 3D structures. This approach enables the fabrication of structures with tunable physicochemical properties and compressibility. Moreover, it facilitates post-functionalization through thiol-Michael addition reactions, thereby expanding performance and application potential.
利用硫醇-烯化学、聚合诱导相分离和数字光处理（DLP）3D打印技术，我们提出了一种制造反应性大孔3D结构的方法。这种方法能够制造出具有可调物理化学性质和可压缩性的结构。此外，它还通过硫醇-迈克尔加成反应促进后功能化，从而扩展了性能和应用潜力。
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