A scandium metalloligand supported Ni(0) complex with a heterobimetallocycle: versatile reactivity with unsaturated bonds.

作者信息

Ma Lei, Pan Xiaowei, Hong Dongjing, Fang Huayi, Cui Peng

机构信息

Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, S 189, Jiuhua Road, Wuhu, Anhui 241002, P. R. China.

School of Materials Science and Engineering, Nankai University, No. 38 Tongyan Road, Haihe Education Park, Tianjin 300350, P. R. China.

出版信息

Chem Commun (Camb). 2024 Apr 11;60(31):4222-4225. doi: 10.1039/d4cc00547c.

DOI:10.1039/d4cc00547c

PMID:38525969

Abstract

A N-bridged tetranuclear Sc(III)-Ni(0) complex featuring a Ni → Sc interaction and a 4-membered [Sc-N-C-Ni] ring was synthesized and characterized. Bimetallic reactivity was demonstrated reactions with a series of unsaturated compounds containing NC, CN, CC, CO and NN bonds.

摘要