一种构建[PtL]笼的动态共价方法。
A dynamic covalent approach to [PtL] cages.
作者信息
van Hilst Quinn V C, Pearcy Aston C, Preston Dan, Wright L James, Hartinger Christian G, Brooks Heather J L, Crowley James D
机构信息
Department of Chemistry, University of Otago, PO Box 56, Dunedin 9054, New Zealand.
The MacDiarmid Institute, Wellington 6140, New Zealand.
出版信息
Chem Commun (Camb). 2024 Apr 16;60(32):4302-4305. doi: 10.1039/d4cc00323c.
A dynamic covalent approach was exploited to generate a family of homometallic [PtL] cage (predominantly [PtL] systems) architectures. The family of platinum(II) architectures were characterized using H nuclear magnetic resonance (NMR) and diffusion ordered spectroscopy (DOSY), electrospray ionization mass spectrometry (ESI-MS) and the molecular structures of two cages were determined by X-ray crystallography.
采用动态共价方法生成了一系列同金属[PtL]笼（主要是[PtL]体系）结构。使用氢核磁共振（NMR）和扩散有序光谱（DOSY）、电喷雾电离质谱（ESI-MS）对该系列铂（II）结构进行了表征，并通过X射线晶体学确定了两个笼的分子结构。
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