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用于光电探测应用的不同有机铵基碘化铋钙钛矿的合成

Synthesis of different organic ammonium-based bismuth iodide perovskites for photodetection application.

作者信息

Elattar Amr, Duclos Cassie, Bellevu Franchesca, Dickens Tarik, Okoli Okenwa

机构信息

Industrial & Manufacturing Engineering, FAMU-FSU College of Engineering 2525 Pottsdamer St. Tallahassee Florida 32310 USA

Herff College of Engineering, University of Memphis Memphis TN 38111 USA.

出版信息

RSC Adv. 2024 Mar 26;14(14):10113-10119. doi: 10.1039/d4ra00173g. eCollection 2024 Mar 20.

DOI:10.1039/d4ra00173g
PMID:38533102
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10964312/
Abstract

Bismuth-based perovskites are promising candidates for highly stable halide perovskites with low toxicity. Here, we report the synthesis of a series of bismuth iodide-based perovskites with different primary, secondary, and tertiary ammonium cations and study their structural, thermal, and optical properties, and the likelihood of photodetection. Interestingly, the variation of A-site organic ammonium cations, with different interlayer spacings between adjacent bismuth iodide monolayers, has exotic effects on the diffraction patterns and morphological structures of the perovskite crystals. Thermogravimetric analysis reveals the highest thermal stability of tertiary ammonium-based bismuth perovskite with a decomposition temperature of 385 °C. The branched primary ammonium-based photodetector has photo-responsivity roughly two and four times faster than that of secondary and tertiary ammonium-based devices, respectively. These findings provide insight into the importance of A-site cation engineering for structural modulation and tailoring the optoelectronic properties of bismuth-based perovskites for emerging optoelectronic devices.

摘要

铋基钙钛矿是具有低毒性的高稳定性卤化物钙钛矿的有前途的候选材料。在此，我们报道了一系列具有不同伯、仲和叔铵阳离子的碘化铋基钙钛矿的合成，并研究了它们的结构、热学和光学性质以及光探测的可能性。有趣的是，A位有机铵阳离子的变化，以及相邻碘化铋单层之间不同的层间距，对钙钛矿晶体的衍射图案和形态结构有奇特的影响。热重分析表明，叔铵基铋钙钛矿具有最高的热稳定性，分解温度为385°C。支链伯铵基光电探测器的光响应速度分别比仲铵基和叔铵基器件快约两倍和四倍。这些发现深入了解了A位阳离子工程对于结构调制以及为新兴光电器件定制铋基钙钛矿光电性质的重要性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f26/10964312/833ef5a73fe4/d4ra00173g-f9.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f26/10964312/b693b1698481/d4ra00173g-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f26/10964312/833ef5a73fe4/d4ra00173g-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f26/10964312/2dec339619af/d4ra00173g-f1.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f26/10964312/9e4e15ce9aba/d4ra00173g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f26/10964312/529096b6ad04/d4ra00173g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f26/10964312/1dcac859d797/d4ra00173g-f6.jpg
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本文引用的文献

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Angew Chem Int Ed Engl. 2023 Aug 28;62(35):e202307646. doi: 10.1002/anie.202307646. Epub 2023 Jul 19.
2
Synthesis and Characterization of High-Efficiency Halide Perovskite Nanomaterials for Light-Absorbing Applications.用于光吸收应用的高效卤化物钙钛矿纳米材料的合成与表征
Ind Eng Chem Res. 2022 Apr 25;62(11):4494-4502. doi: 10.1021/acs.iecr.2c00416. eCollection 2023 Mar 22.
3
A universal all-solid synthesis for high throughput production of halide perovskite.
一种用于高通量生产卤化物钙钛矿的通用全固态合成方法。
Nat Commun. 2022 Dec 1;13(1):7399. doi: 10.1038/s41467-022-35122-7.
4
Long-range charge carrier mobility in metal halide perovskite thin-films and single crystals via transient photo-conductivity.通过瞬态光电导率研究金属卤化物钙钛矿薄膜和单晶中的长程电荷载流子迁移率。
Nat Commun. 2022 Jul 20;13(1):4201. doi: 10.1038/s41467-022-31569-w.
5
Revealing Weak Dimensional Confinement Effects in Excitonic Silver/Bismuth Double Perovskites.揭示激子型银/铋双钙钛矿中的弱维度限制效应
JACS Au. 2021 Dec 17;2(1):136-149. doi: 10.1021/jacsau.1c00429. eCollection 2022 Jan 24.
6
Environmental lead exposure from halide perovskites in solar cells.太阳能电池卤化物钙钛矿中的环境铅暴露。
Trends Ecol Evol. 2022 Apr;37(4):281-283. doi: 10.1016/j.tree.2022.01.002. Epub 2022 Jan 25.
7
Metal halide perovskite toxicity effects on plants are caused by iodide ions.金属卤化物钙钛矿对植物的毒性作用是由碘离子引起的。
iScience. 2021 Dec 9;25(1):103583. doi: 10.1016/j.isci.2021.103583. eCollection 2022 Jan 21.
8
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J Hazard Mater. 2022 Mar 15;426:127848. doi: 10.1016/j.jhazmat.2021.127848. Epub 2021 Nov 20.
9
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