Liu Fu, Li Fangfang, Li Xuelei, Tian Haobin, Lei Xudong
School of Intelligent Manufacturing and Control Engineering, Shanghai Polytechnic University, Shanghai 201209, China.
Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, China.
Polymers (Basel). 2024 Mar 13;16(6):804. doi: 10.3390/polym16060804.
In this study, the traditional mini split Hopkinson tension bar (SHTB) was enhanced for the dynamic mechanical performance testing of single fiber/resin interface of composites. Single Aramid III fibers were modified using a polyamine modification treatment. Quasi-static and dynamic tensile tests of modified single Aramid III fibers were conducted using an electronic tensile testing machine and mini SHTB. The test results indicated that the surface modification employing the Catechol-Tetraethylenepentamine (Cat-TEPA) approach had a negligible effect on the tensile mechanical properties of single Aramid III fibers. The microdroplet method was introduced to measure the dynamic interfacial shear strength (IFSS) of Aramid III fiber/waterborne polyurethane resin using a mini SHTB. The dynamic shear test results revealed an increase in the dynamic shear strength of the modified Aramid III fiber/resin interface from 36.16 MPa to 41.51 MPa. Furthermore, the Scanning Electron Microscope (SEM) photography of the modified single Aramid III fiber after debonding exhibited regular grid structures on the debonding area, which can prevent debonding between the single fiber and the microdroplet, thereby enhancing interfacial shear performance.
在本研究中,对传统的小型分体式霍普金森拉杆(SHTB)进行了改进,用于复合材料单纤维/树脂界面的动态力学性能测试。采用多胺改性处理对单根芳纶III纤维进行改性。使用电子拉伸试验机和小型SHTB对改性后的单根芳纶III纤维进行了准静态和动态拉伸试验。试验结果表明,采用邻苯二酚-五乙烯六胺(Cat-TEPA)方法进行表面改性对单根芳纶III纤维的拉伸力学性能影响可忽略不计。引入微滴法,使用小型SHTB测量芳纶III纤维/水性聚氨酯树脂的动态界面剪切强度(IFSS)。动态剪切试验结果表明,改性芳纶III纤维/树脂界面的动态剪切强度从36.16MPa提高到41.51MPa。此外,脱粘后改性单根芳纶III纤维的扫描电子显微镜(SEM)照片显示,脱粘区域呈现规则的网格结构,可防止单纤维与微滴之间的脱粘,从而提高界面剪切性能。