Suppr超能文献

通过局部高电场控制击穿在聚甲基丙烯酸甲酯膜上快速制备纳米孔

Fast Fabrication Nanopores on a PMMA Membrane by a Local High Electric Field Controlled Breakdown.

作者信息

Fang Shaoxi, Zeng Delin, He Shixuan, Li Yadong, Pang Zichen, Wang Yunjiao, Liang Liyuan, Weng Ting, Xie Wanyi, Wang Deqiang

机构信息

Chongqing Key Laboratory of Multi-Scale Manufacturing Technology, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China.

Chongqing School, University of Chinese Academy of Sciences, Chongqing 400714, China.

出版信息

Sensors (Basel). 2024 Mar 26;24(7):2109. doi: 10.3390/s24072109.

Abstract

The sensitivity and accuracy of nanopore sensors are severely hindered by the high noise associated with solid-state nanopores. To mitigate this issue, the deposition of organic polymer materials onto silicon nitride (SiNx) membranes has been effective in obtaining low-noise measurements. Nonetheless, the fabrication of nanopores sub-10 nm on thin polymer membranes remains a significant challenge. This work proposes a method for fabricating nanopores on polymethyl methacrylate (PMMA) membrane by the local high electrical field controlled breakdown, exploring the impact of voltage and current on the breakdown of PMMA membranes and discussing the mechanism underlying the breakdown voltage and current during the formation of nanopores. By improving the electric field application method, transient high electric fields that are one-seven times higher than the breakdown electric field can be utilized to fabricate nanopores. A comparative analysis was performed on the current noise levels of nanopores in PMMA-SiNx composite membranes and SiNx nanopores with a 5 nm diameter. The results demonstrated that the fast fabrication of nanopores on PMMA-SiNx membranes exhibited reduced current noise compared to SiNx nanopores. This finding provides evidence supporting the feasibility of utilizing this technology for efficiently fabricating low-noise nanopores on polymer composite membranes.

摘要

与固态纳米孔相关的高噪声严重阻碍了纳米孔传感器的灵敏度和准确性。为了缓解这一问题,在氮化硅(SiNx)膜上沉积有机聚合物材料对于获得低噪声测量结果是有效的。尽管如此,在薄聚合物膜上制造小于10纳米的纳米孔仍然是一项重大挑战。这项工作提出了一种通过局部高电场控制击穿在聚甲基丙烯酸甲酯(PMMA)膜上制造纳米孔的方法,探索电压和电流对PMMA膜击穿的影响,并讨论纳米孔形成过程中击穿电压和电流的潜在机制。通过改进电场施加方法,可以利用比击穿电场高1至7倍的瞬态高电场来制造纳米孔。对PMMA-SiNx复合膜中的纳米孔和直径为5纳米的SiNx纳米孔的电流噪声水平进行了对比分析。结果表明,与SiNx纳米孔相比,在PMMA-SiNx膜上快速制造纳米孔表现出更低的电流噪声。这一发现为利用该技术在聚合物复合膜上高效制造低噪声纳米孔的可行性提供了证据支持。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/beca/11013984/ae4a7a93ac43/sensors-24-02109-g001.jpg

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验