Hong Seong Gyun, Oh Byeong M, Kim Jong H, Lee Jea Uk
Department of Advanced Materials Engineering for Information and Electronics, Integrated Education Institute for Frontier Science and Technology (BK21 Four), Kyung Hee University, 1732 De-ogyeong-daero, Giheung-gu, Yongin-si 17104, Gyeonggi-do, Republic of Korea.
Department of Molecular Science and Technology, Ajou University, 206, World Cup-ro, Yeongtong-gu, Suwon-si 16499, Gyeonggi-do, Republic of Korea.
Materials (Basel). 2024 Apr 11;17(8):1745. doi: 10.3390/ma17081745.
This study demonstrates a novel methodology for developing a textile-based adsorption sensor via mixed solvent dyeing with aggregation-induced emission (AIE) dyes on recycled fabrics. AIE dyes were incorporated into the fabrics using a mixed solvent dyeing method with a co-solvent mixture of HO and organic solvents. This method imparted unique fluorescence properties to fabrics, altering fluorescence intensity or wavelength based on whether the AIE dye molecules were in an isolated or aggregated state on the fabrics. The precise control of the HO fraction to organic solvent during dyeing was crucial for influencing fluorescence intensity and sensing characteristics. These dyed fabrics exhibited reactive thermochromic and vaporchromic properties, with changes in fluorescence intensity corresponding to variations in temperature and exposure to volatile organic solvents (VOCs). Their superior characteristics, including a repetitive fluorescence switching property and resistance to photo-bleaching, enhance their practicality across various applications. Consequently, the smart fabrics dyed with AIE dye not only find applications in clothing and fashion design but demonstrate versatility in various fields, extending to sensing temperature, humidity, and hazardous chemicals.
本研究展示了一种通过在回收织物上用聚集诱导发光(AIE)染料进行混合溶剂染色来开发基于纺织品的吸附传感器的新方法。使用含有HO和有机溶剂的共溶剂混合物的混合溶剂染色方法将AIE染料掺入织物中。这种方法赋予织物独特的荧光特性,根据AIE染料分子在织物上处于孤立状态还是聚集状态来改变荧光强度或波长。染色过程中HO与有机溶剂比例的精确控制对于影响荧光强度和传感特性至关重要。这些染色织物表现出反应性热致变色和气相变色特性,荧光强度的变化对应于温度变化和暴露于挥发性有机溶剂(VOCs)的情况。它们的优异特性,包括重复荧光切换特性和抗光漂白性,增强了其在各种应用中的实用性。因此,用AIE染料染色的智能织物不仅可应用于服装和时尚设计,还在各个领域展现出多功能性,扩展到传感温度、湿度和有害化学物质。