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将 spp. 灰烬用作砂浆生产的原材料:复合性能与环境展望。

The Use of spp. Ashes Like a Raw Material for Mortar Production: Composite Performance and Environmental Outlook.

作者信息

Lyra Gabriela Pitolli, Colombo Ana Letícia, Duran Afonso José Felício Peres, Parente Igor Machado da Silva, Bueno Cristiane, Rossignolo João Adriano

机构信息

Department of Biosystems Engineering, Faculty of Animal Science and Food Engineering, Universidade de São Paulo (USP), Pirassununga 13635-900, Brazil.

Post-Graduation Program in Material Science and Engineering, Faculty of Animal Science and Food Engineering, Universidade de São Paulo (USP), Pirassununga 13635-900, Brazil.

出版信息

Materials (Basel). 2024 Apr 12;17(8):1785. doi: 10.3390/ma17081785.

Abstract

The accumulation of brown algae from the genus has been increasing over the years in coastal regions of the Caribbean, Africa, Brazil, and Mexico. This causes harmful effects to the ecosystem, human health, the economy, and the climate due to gas emissions from its decomposition process. There is the possibility of this biomass being reused in civil construction, and some studies have been carried out on its application to common Portland cement mortar. As such, the objective of this study is to evaluate the potential of sargassum ash as a mineral addition to partially replace fine aggregates in Portland cement mortar. Characterization of the raw materials was carried out through X-ray fluorescence spectroscopy, loss on ignition, particle size distribution, Brunauer-Emmett-Teller (BET) analysis, real density, X-ray diffraction, scanning electron microscopy, and dispersion spectroscopy of electrons. The mortars were prepared by partially replacing the fine aggregate (sand) with sargassum ash at 0%, 5%, 10%, and 20%. Mortar performance was evaluated through water absorption, apparent porosity, apparent specific mass, and compressive strength 7, 28, and 63 days after curing. Lastly, a life cycle assessment was conducted in accordance with ISO standards 14040:2006 and 14044:2006. The results showed that replacing sand with sargassum ash increases water absorption and apparent porosity, and decreases the apparent specific mass and compressive strength as replacement increases. Nevertheless, the compressive strength results after 63 days for 5 and 10% replacement did not differ statistically from reference values. The life cycle assessment indicated that mortars with partial replacement of sand by sargassum ash show positive environmental impacts when compared to reference values for most categories, regardless of the scenario analyzed, especially for mortar with 10% replacement. As such, the use of sargassum ash at 10% does not alter the mortar's compressive strength values after 63 days, but does reduce its environmental impact. The application of this biomass in civil construction materials provides a destination for this algae, and that can be a solution to mitigate the social, environmental, and economic problems it has been causing.

摘要

多年来,加勒比地区、非洲、巴西和墨西哥沿海地区马尾藻属褐藻的堆积量一直在增加。由于其分解过程中产生的气体排放,这对生态系统、人类健康、经济和气候造成了有害影响。这种生物质有可能在民用建筑中得到再利用,并且已经针对其在普通波特兰水泥砂浆中的应用开展了一些研究。因此,本研究的目的是评估马尾藻灰作为矿物掺合料部分替代波特兰水泥砂浆中细集料的潜力。通过X射线荧光光谱法、灼烧减量、粒度分布、布鲁诺尔-埃米特-泰勒(BET)分析、真密度、X射线衍射、扫描电子显微镜和电子能谱对原材料进行了表征。通过用0%、5%、10%和20%的马尾藻灰部分替代细集料(砂)来制备砂浆。在养护7天、28天和63天后,通过吸水率、表观孔隙率、表观比重和抗压强度对砂浆性能进行了评估。最后,按照ISO标准14040:2006和14044:2006进行了生命周期评估。结果表明,用马尾藻灰替代砂会增加吸水率和表观孔隙率,并随着替代量的增加而降低表观比重和抗压强度。然而,5%和10%替代量的砂浆在63天后的抗压强度结果与参考值在统计学上没有差异。生命周期评估表明,与参考值相比,部分用马尾藻灰替代砂的砂浆在大多数类别中显示出积极的环境影响,无论分析的是哪种情况,特别是对于10%替代量的砂浆。因此,10%的马尾藻灰用量在63天后不会改变砂浆的抗压强度值,但会降低其环境影响。这种生物质在民用建筑材料中的应用为这种藻类提供了一个归宿,并且可以成为缓解其一直造成的社会、环境和经济问题的一种解决方案。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c625/11051454/33f1fe3e3449/materials-17-01785-g001.jpg

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