可见光促进的乙烯基叠氮化物与全氟烷基取代的亚胺基硫鎓叶立德的[3+2]环化反应。
Visible light-promoted [3+2] cyclization reaction of vinyl azides with perfluoroalkyl-substituted-imidoyl sulfoxonium ylides.
作者信息
Yang Ming, Meng Yu-Xuan, Mehfooz Haroon, Zhao Yu-Long
机构信息
Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University, Changchun 130024, China.
出版信息
Chem Commun (Camb). 2024 May 16;60(41):5407-5410. doi: 10.1039/d4cc00777h.
Visible-light-induced [3+2] cyclization of vinyl azides with perfluoroalkyl-substituted imidoyl sulfoxonium ylides has been developed for the first time. In this transformation, perfluoroalkyl-substituted imidoyl sulfoxonium ylides are firstly employed as a carbon radical precursor under visible light irradiation, providing a new and efficient method for the construction of perfluoroalkyl-substituted 1-pyrrolines.
首次开发了可见光诱导的乙烯基叠氮化物与全氟烷基取代的亚胺基硫鎓叶立德的[3+2]环化反应。在该转化过程中，全氟烷基取代的亚胺基硫鎓叶立德首次在可见光照射下用作碳自由基前体，为构建全氟烷基取代的1-吡咯啉提供了一种新的有效方法。
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