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用于二氧化碳捕获、利用和储存技术的二氧化碳捕获材料研究综述

Research on carbon dioxide capture materials used for carbon dioxide capture, utilization, and storage technology: a review.

作者信息

Dang Hongtao, Guan Bin, Chen Junyan, Ma Zeren, Chen Yujun, Zhang Jinhe, Guo Zelong, Chen Lei, Hu Jingqiu, Yi Chao, Yao Shunyu, Huang Zhen

机构信息

Key Laboratory for Power Machinery and Engineering of Ministry of Education, Shanghai Jiao Tong University, Shanghai, 200240, China.

出版信息

Environ Sci Pollut Res Int. 2024 May;31(23):33259-33302. doi: 10.1007/s11356-024-33370-2. Epub 2024 May 3.

Abstract

In recent years, climate change has increasingly become one of the major challenges facing mankind today, seriously threatening the survival and sustainable development of mankind. Dramatically increasing carbon dioxide concentrations are thought to cause a severe greenhouse effect, leading to severe and sustained global warming, associated climate instability and unwelcome natural disasters, melting glaciers and extreme weather patterns. The treatment of flue gas from thermal power plants uses carbon capture, utilization, and storage (CCUS) technology, one of the most promising current methods to accomplish significant CO emission reduction. In order to implement the technological and financial system of CO capture, which is the key technology of CCUS technology and accounts for 70-80% of the overall cost of CCUS technology, it is crucial to create more effective adsorbents. Nowadays, with the development and application of various carbon dioxide capture materials, it is necessary to review and summarize carbon dioxide capture materials in time. In this paper, the main technologies of CO capture are reviewed, with emphasis on the latest research status of CO capture materials, such as amines, zeolites, alkali metals, as well as emerging MOFs and carbon nanomaterials. More and more research on CO capture materials has used a variety of improved methods, which have achieved high CO capture performance. For example, doping of layered double hydroxides (LDH) with metal atoms significantly increases the active site on the surface of the material, which has a significant impact on improving the CO capture capacity and performance stability of LDH. Although many carbon capture materials have been developed, high cost and low technology scale remain major obstacles to CO capture. Future research should focus on designing low-cost, high-availability carbon capture materials.

摘要

近年来,气候变化日益成为当今人类面临的主要挑战之一,严重威胁着人类的生存和可持续发展。二氧化碳浓度急剧增加被认为会导致严重的温室效应,引发严重且持续的全球变暖、相关的气候不稳定以及不受欢迎的自然灾害,如冰川融化和极端天气模式。火力发电厂烟气处理采用碳捕获、利用与封存(CCUS)技术,这是目前实现大幅减排最具前景的方法之一。为了实施作为CCUS技术关键技术且占CCUS技术总成本70 - 80%的碳捕获技术和金融体系,开发更有效的吸附剂至关重要。如今,随着各种二氧化碳捕获材料的发展与应用,及时对二氧化碳捕获材料进行综述和总结很有必要。本文综述了碳捕获的主要技术,重点介绍了二氧化碳捕获材料的最新研究现状,如胺类、沸石、碱金属以及新兴的金属有机框架材料(MOFs)和碳纳米材料。越来越多关于二氧化碳捕获材料的研究采用了各种改进方法,取得了较高的二氧化碳捕获性能。例如,用金属原子掺杂层状双氢氧化物(LDH)显著增加了材料表面的活性位点,这对提高LDH的二氧化碳捕获能力和性能稳定性有显著影响。尽管已经开发了许多碳捕获材料,但高成本和低技术规模仍然是碳捕获的主要障碍。未来的研究应集中在设计低成本、高可用性的碳捕获材料上。

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