Piedra Helena F, Plaza Manuel
Departamento de Química Orgánica e Inorgánica and Instituto Universitario de Química Organometálica "Enrique Moles" and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Universidad de Oviedo, Julián Clavería, 8, 33006, Oviedo, Spain.
Photochem Photobiol Sci. 2024 Jun;23(6):1217-1228. doi: 10.1007/s43630-024-00580-z. Epub 2024 May 3.
In recent years, visible-light-induced organic transformations have taken a central role driving forward the progress of modern organic synthesis. These processes typically involve the transient generation of highly reactive radical intermediates, facilitating a diverse array of chemical reactions. Despite the abundance of synthetic strategies enabling the access of aryl and alkyl-centered radicals, the exploitation of photochemistry to generate highly reactive alkenyl radicals has remained notably underdeveloped. In this review, we present recent advancements in visible-light-induced transformations that proceed through the generation of alkenyl radicals from alkenyl-containing precursors, predominantly alkenyl halides, showcasing their application in various organic transformations.
近年来，可见光诱导的有机转化在推动现代有机合成进展方面发挥了核心作用。这些过程通常涉及高活性自由基中间体的瞬态生成，促进了各种各样的化学反应。尽管有大量合成策略可用于生成芳基和烷基中心的自由基，但利用光化学生成高活性烯基自由基的研究仍明显不足。在本综述中，我们介绍了可见光诱导转化的最新进展，这些转化通过从含烯基前体（主要是烯基卤化物）生成烯基自由基来进行，并展示了它们在各种有机转化中的应用。
