Room-Temperature Synthesis and Low Thermal Conductivity in Nanocrystalline AgCuS.

Noble-metal-based chalcogenide materials recently gained massive attention in the field of thermoelectrics. In most cases, materials are synthesized using (i) high-temperature solid-state reactions or (ii) soft chemical methods where temperature requirements are lower than those of solid-state reactions (generally below 400 °C). Herein, we present a simple, surfactant-free, room-temperature, and energy-efficient synthesis of AgCuS nanocrystals. The present synthesis technique is scalable and capable of gram-scale production. A spark plasma sintering (SPS) pressed sample exhibits ultralow thermal conductivity (∼0.31 W/mK at room temperature). We found that AgCuS exhibits low sound velocity, as well as a non-Debye-like behavior based on a low-temperature heat capacity measurement. A high degree of anharmonicity of bonding, soft vibrations modes, and nanoscale grain boundary scattering in AgCuS lead to ultralow thermal conductivity, which can be important for thermoelectrics, optoelectronics, and thermal barrier coating applications.