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表面活性剂的电化学氧化是实现中水回用的关键步骤。

Electrochemical oxidation of surfactants as an essential step to enable greywater reuse.

作者信息

Dos Santos Alexsandro J, Shen Hongchen, Lanza Marcos R V, Li Qilin, Garcia-Segura Sergi

机构信息

Nanosystems Engineering Research Center for Nanotechnology-Enabled Water Treatment, School of Sustainable Engineering and the Built Environment, Arizona State University, Tempe, AZ 85287-3005, United States.

São Carlos Institute of Chemistry, University of São Paulo, Avenida Trabalhador São Carlense 400, São Carlos, SP 13566-590, Brazil.

出版信息

Environ Technol Innov. 2024 May;34:103563. doi: 10.1016/j.eti.2024.103563.

DOI:10.1016/j.eti.2024.103563
PMID:38706941
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11066849/
Abstract

The practical application of electrochemical oxidation technology for the removal of surfactants from greywater was evaluated using sodium dodecyl sulfate (SDS) as a model surfactant. Careful selection of electrocatalysts and optimization of operational parameters demonstrated effective SDS removal in treating a complex greywater matrix with energy consumption below 1 kWh g COD (Chemical Oxygen Demand), paving the way for a more sustainable approach to achieving surfactant removal in greywater treatment when aiming for decentralized water reuse. Chromatographic techniques identified carboxylic acids as key byproducts prior to complete mineralization. These innovative approaches represent a novel pathway for harnessing electrochemical technologies within decentralized compact devices, offering a promising avenue for further advancements in this field.

摘要

以十二烷基硫酸钠(SDS)作为模型表面活性剂,评估了电化学氧化技术在去除中水表面活性剂方面的实际应用。通过精心选择电催化剂和优化操作参数,在处理复杂的中水基质时实现了有效的SDS去除,能耗低于1 kWh/g COD(化学需氧量),为在分散式水回用目标下实现中水表面活性剂去除提供了更具可持续性的方法。色谱技术确定羧酸是完全矿化之前的关键副产物。这些创新方法代表了在分散式紧凑型设备中利用电化学技术的新途径,为该领域的进一步发展提供了有前景的方向。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bda6/11066849/b9626b055a16/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bda6/11066849/80d2d5bd92bd/ga1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bda6/11066849/30f515c7077e/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bda6/11066849/57dbca6a92ef/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bda6/11066849/618701486f62/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bda6/11066849/1e4dbe0d9411/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bda6/11066849/b9626b055a16/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bda6/11066849/80d2d5bd92bd/ga1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bda6/11066849/30f515c7077e/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bda6/11066849/57dbca6a92ef/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bda6/11066849/618701486f62/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bda6/11066849/1e4dbe0d9411/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bda6/11066849/b9626b055a16/gr5.jpg

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