Deng Zhiying, Li Zhiwei, Li Peng, Wu Wenchao, Xiong Liwei, Zhang Zhanhui, Yang Yuxi, Cheng Youyou
Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, Wuhan Institute of Technology, Wuhan 430205, P. R. China.
National Engineering Laboratory for Exploration and Development of Low-Permeability Oil and Gas Field, Xi'an 710018, P. R. China.
ACS Omega. 2024 Apr 18;9(17):19043-19050. doi: 10.1021/acsomega.3c07863. eCollection 2024 Apr 30.
There have been few studies on the role of nanofluids in oil displacement and injection parameters, despite their significant impact on the oil displacement effect. To enhance oil recovery in an ultralow-permeability reservoir, the nanosized oil-displacement agent with nano-SiO modified by a silane coupling agent as a main component was selected for the first time in the Changqing oilfield. To assess the performance of the nanofluid, various factors such as particle size, contact angle, interfacial tension, and emulsion stability were taken into consideration. The oil displacement effect of nanofluids was evaluated by a microscopic model and ultralow-permeability core displacement experiment, and its optimal injection parameters were determined. The average particle size of the nano-oil displacement agent is 22-30 nm. It can change the wetting condition of the rock from oil-wet to water-wet and reduce the oil-water interfacial tension. Even at 80 °C, the emulsion formed by the agent remained stable. The oil displacement experiment shows that the nano-oil displacement agent whose injection pressure increases can displace the residual oil trapped in small pores that cannot be affected by conventional water flooding. The injection mode of "nanoflooding agent drive + water drive + nanoflooding agent drive", injection rate of 0.1 mL/min, injection concentration of 0.5%, and injection volume of 0.5 PV (0.25 PV per segment), which can effectively guide the injection of the oil displacement agent, achieve the best oil displacement effect.
尽管纳米流体对驱油效果有显著影响,但关于其在驱油和注入参数方面作用的研究却很少。为提高超低渗透油藏的采收率,长庆油田首次选用以硅烷偶联剂改性的纳米SiO为主要成分的纳米驱油剂。为评估纳米流体的性能,考虑了粒径、接触角、界面张力和乳液稳定性等各种因素。通过微观模型和超低渗透岩心驱替实验评估了纳米流体的驱油效果,并确定了其最佳注入参数。纳米驱油剂的平均粒径为22-30nm。它可以将岩石的润湿性从油湿转变为水湿,并降低油水界面张力。即使在80℃时,该剂形成的乳液仍保持稳定。驱油实验表明,注入压力增加的纳米驱油剂能够驱替常规水驱无法影响的小孔隙中滞留的残余油。采用“纳米驱油剂驱+水驱+纳米驱油剂驱”的注入方式,注入速率为0.1mL/min,注入浓度为0.5%,注入体积为0.5PV(每段0.25PV),可有效指导驱油剂的注入,达到最佳驱油效果。