Soria-Castro Montserrat, Genescá-Llongueras Juan, Hernández-Bolio Gloria Ivonne, Castro-Borges Pedro
Unidad de Investigación y Tecnología Aplicadas, UNITA, Facultad Química, UNAM. Parque de Investigación e Innovación Tecnológica, PIIT 66628 Apodaca NL Mexico.
Departamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados del IPN Unidad Mérida Yucatán Mexico
RSC Adv. 2024 May 13;14(22):15468-15482. doi: 10.1039/d4ra00690a. eCollection 2024 May 10.
The present investigation establishes the basis for future studies in the southeast of México for the improvement of building materials by combining regional organic and inorganic nanoparticles in admixtures to formulate cement mortars with durability potential in structures of concrete. The characterization of the organic extract of by nuclear magnetic resonance (NMR) revealed the presence of epicatechin (tannin related) and sucrose. Calcium zinc hydroxide dihydrate nanoparticles (CZ NPs) showed the highest surface area of 60.7 m g. The electrical resistivity, propagation of ultrasound velocity and water absorption by capillarity properties were individually evaluated for the organic extract, the inorganic nanoparticles and their admixtures in cement mortars, at a curing time of 7, 28 and 96 days with and optimal concentration of 5 mg mL of the added additives. The best results were obtained at 96 days showing slightly but clear improvement of the electrical resistivity (23.40 ± 0.022 kΩ cm, 22.40 ± 0.004 kΩ cm and 22.29 ± 0.013 kΩ cm), propagation of ultrasound velocity (1370 ± 10 m s, 1345 m s ± 6, 1310 ± 9 m s) and capillary coefficient (0.0044 kg ms, 0.0045 kg ms and 0.0049 kg ms) properties of the cement mortars with CZ NPs, extraction solution (EAS) and CZ NPs + EAS respectively when compared to the mortar control (19.91 ± 0.036 kΩ cm, 1266 ± 15 m s and 0.0082 kg ms).
本研究为墨西哥东南部未来的研究奠定了基础,该研究旨在通过将区域有机和无机纳米颗粒混合,以改进建筑材料,从而配制出在混凝土结构中具有耐久性潜力的水泥砂浆。通过核磁共振(NMR)对有机提取物进行表征,结果显示存在表儿茶素(与单宁相关)和蔗糖。二水合氢氧化钙锌纳米颗粒(CZ NPs)的比表面积最高,为60.7 m²/g。分别对有机提取物、无机纳米颗粒及其在水泥砂浆中的混合物在7天、28天和96天的养护时间下,以及添加添加剂的最佳浓度为5 mg/mL时的水泥砂浆的电阻率、超声速传播和毛细吸水率进行了评估。在96天时获得了最佳结果,与对照砂浆(19.91±0.036 kΩ·cm、1266±15 m/s和0.0082 kg/(m·s))相比,含有CZ NPs、提取物溶液(EAS)和CZ NPs + EAS的水泥砂浆的电阻率(23.40±0.022 kΩ·cm、22.40±0.004 kΩ·cm和22.