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高级光催化作为一种可行且可持续的废水处理工艺:全面综述。

Advanced photocatalysis as a viable and sustainable wastewater treatment process: A comprehensive review.

机构信息

Department of Chemistry, Government College University Lahore, Pakistan.

Division of Science and Technology, University of Education Lahore, Pakistan.

出版信息

Environ Res. 2024 Jul 15;253:118947. doi: 10.1016/j.envres.2024.118947. Epub 2024 May 12.

Abstract

In our era, water pollution not only poses a serious threat to human, animal, and biotic life but also causes serious damage to infrastructure and the ecosystem. A set of physical, chemical, and biological technologies have been exploited to decontaminate and/or disinfect water pollutants, toxins, microbes, and contaminants, but none of these could be ranked as sustainable and scalable wastewater technology. The photocatalytic process can harmonize the sunlight to degrade certain toxins, chemicals, microbes, and antibiotics, present in water. For example, transition metal oxides (ZnO, SnO, TiO, etc.), when integrated into an organic framework of graphene or nitrides, can bring about more than 90% removal of dyes, microbial load, pesticides, and antibiotics. Similarly, a modified network of graphitic carbon nitride can completely decontaminate petrochemicals. The present review will primarily highlight the mechanistic aspects for the removal and/or degradation of highly concerned contaminants, factors affecting photocatalysis, engineering designs of photoreactors, and pros and cons of various wastewater treatment technologies already in practice. The photocatalytic reactor can be a more viable and sustainable wastewater treatment opportunity. We hope the researcher will find a handful of information regarding the advanced oxidation process accomplished via photocatalysis and the benefits associated with the photocatalytic-type degradation of water pollutants and contaminants.

摘要

在我们这个时代,水污染不仅对人类、动物和生物生命构成严重威胁,而且还对基础设施和生态系统造成严重破坏。已经开发了一系列物理、化学和生物技术来净化和/或消毒水污染物、毒素、微生物和污染物,但没有一种技术可以被评为可持续和可扩展的废水处理技术。光催化过程可以利用阳光来降解水中存在的某些毒素、化学品、微生物和抗生素。例如,过渡金属氧化物(ZnO、SnO、TiO 等)与石墨烯或氮化物的有机框架结合时,可以去除 90%以上的染料、微生物负荷、农药和抗生素。同样,经过改良的石墨相氮化碳网络可以完全净化石化产品。本综述将主要强调去除和/或降解高度关注的污染物的机制方面、影响光催化的因素、光反应器的工程设计以及已经实际应用的各种废水处理技术的优缺点。光催化反应器可能是一种更可行和可持续的废水处理机会。我们希望研究人员能够找到一些有关通过光催化完成的高级氧化过程的信息,以及与光催化型水污染物和污染物降解相关的好处。

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