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ZnGeO纳米磷光体的可控合成及其形貌依赖的发光效率

Controllable synthesis and morphology-dependent light emission efficiency of ZnGeO nanophosphors.

作者信息

Tinoco Miguel, Lendínez José Miguel, González-Calbet José M, Méndez Bianchi, Ramírez-Castellanos Julio, Hidalgo Pedro

机构信息

Departamento de Química Inorgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid Madrid 28020 Spain

Departamento de Física de Materiales, Facultad de Ciencias Físicas, Universidad Complutense de Madrid Madrid 28020 Spain

出版信息

Nanoscale Adv. 2024 Apr 4;6(10):2722-2727. doi: 10.1039/d4na00018h. eCollection 2024 May 14.

DOI:10.1039/d4na00018h
PMID:38752134
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11093258/
Abstract

ZnGeO is considered a very promising alternative to current luminescent semiconductors. Previous results suggest that its emitted wavelength may depend on different variables, such as particle size and morphology, among others. In this work, we have prepared pure and highly homogeneous ZnGeO nanorods under hydrothermal synthesis conditions with a willemite-like structure. Their luminescent properties have been explored and their band gap is estimated, which are distinct from those of previously reported ZnGeO bulk particles. Therefore, our results identify particle morphology as a crucial factor for maximizing and fine-tuning the luminescence of ZnGeO nano-phosphors.

摘要

ZnGeO被认为是当前发光半导体非常有前景的替代物。先前的结果表明,其发射波长可能取决于不同变量,如粒径和形态等。在这项工作中,我们在水热合成条件下制备了具有硅锌矿结构的纯净且高度均匀的ZnGeO纳米棒。我们探究了它们的发光特性并估计了其带隙,这些与先前报道的ZnGeO块状颗粒不同。因此,我们的结果表明颗粒形态是最大化和微调ZnGeO纳米磷光体发光的关键因素。

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本文引用的文献

1
Anisotropic nanomaterials for shape-dependent physicochemical and biomedical applications.各向异性纳米材料用于依赖形状的物理化学和生物医学应用。
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Luminescence properties and the thermal quenching mechanism of Mn doped ZnGeO long persistent phosphors.Mn掺杂ZnGeO长余辉荧光粉的发光特性及热猝灭机制
Dalton Trans. 2018 Jan 23;47(4):1303-1311. doi: 10.1039/c7dt03906a.
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One-Dimensional Luminous Nanorods Featuring Tunable Persistent Luminescence for Autofluorescence-Free Biosensing.
一维上转换纳米棒具有可调谐的持续发光特性,可用于无自发荧光的生物传感。
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Opt Express. 2012 Jan 30;20(3):2982-91. doi: 10.1364/OE.20.002982.
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TiO2 nanotubes: synthesis and applications.TiO2 纳米管:合成与应用。
Angew Chem Int Ed Engl. 2011 Mar 21;50(13):2904-39. doi: 10.1002/anie.201001374. Epub 2011 Mar 10.