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将CO引入有机硫化合物中的最新趋势——C-S键断裂。

Recent trends in incorporation of CO into organosulfur compounds C-S bond cleavage.

作者信息

Zainul Rahadian, Abdullah Media Noori, Saeed Shakir Mahmood, Idan Ameer Hassan, Ahmed Alsultany Nahed Mahmood, Arshadi Sattar, Behmagham Farnaz, Vessally Esmail

机构信息

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Padang Indonesia.

Center for Advanced Material Processing, Artificial Intelligence, and Biophysics Informatics (CAMPBIOTICS), Universitas Negeri Padang Indonesia.

出版信息

RSC Adv. 2024 May 15;14(22):15680-15690. doi: 10.1039/d4ra02405b. eCollection 2024 May 10.

DOI:10.1039/d4ra02405b
PMID:38752156
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11095090/
Abstract

Desulfurative functionalization of organosulfur compounds to form various carbon-carbon and carbon-heteroatom bonds has become established as a powerful tool in organic chemistry. In this context, desulfurative carboxylation of this class of compounds using carbon dioxide (CO) as a sustainable and renewable source of carboxyl has recently been developed as an efficient option for the synthesis of carboxylic acid derivatives. The aim of this Focus Review is to summarize the major progress in this appealing research field with particular emphasis on the mechanistic features of the reactions. Literature has been surveyed until the end of February 2024, according to the data collected using SciFinder and Google Scholar engines.

摘要

有机硫化合物的脱硫官能团化反应以形成各种碳-碳键和碳-杂原子键，已成为有机化学中一种强大的工具。在此背景下，最近开发了以二氧化碳（CO₂）作为可持续且可再生的羧基来源，对这类化合物进行脱硫羧基化反应，作为合成羧酸衍生物的一种有效方法。本重点综述的目的是总结这一引人关注的研究领域的主要进展，特别强调反应的机理特征。根据使用SciFinder和谷歌学术搜索引擎收集的数据，对截至2024年2月底的文献进行了调研。

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本文引用的文献

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Recent progress in reductive carboxylation of C-O bonds with CO.一氧化碳参与的碳-氧键还原羧化反应的最新进展
RSC Adv. 2023 Nov 3;13(46):32502-32517. doi: 10.1039/d3ra04073a. eCollection 2023 Oct 31.
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Electroreductive Desulfurative Transformations with Thioethers as Alkyl Radical Precursors.以硫醚作为烷基自由基前体的电还原脱硫转化反应。
Angew Chem Int Ed Engl. 2023 Sep 25;62(39):e202304272. doi: 10.1002/anie.202304272. Epub 2023 Jul 21.
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Carboxylic Acid Derivatives in Herbicide Development.除草剂开发中的羧酸衍生物。
J Agric Food Chem. 2023 Jul 5;71(26):9973-9993. doi: 10.1021/acs.jafc.3c00951. Epub 2023 Jun 20.
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Transition-metal-free C-S bond cleavage and transformation of organosulfur compounds.无过渡金属参与的 C-S 键断裂及有机硫化合物的转化。
Chem Commun (Camb). 2023 May 2;59(36):5343-5364. doi: 10.1039/d3cc00377a.
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Organothianthrenium salts: synthesis and utilization.有机噻蒽鎓盐：合成与应用
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