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二维石墨炔的性质、合成及新兴应用:近期进展综述。

Properties, Synthesis and Emerging Applications of Graphdiyne: A Journey Through Recent Advancements.

机构信息

CHRIST (Deemed to Be University), Bangalore, Karnataka, 560029, India.

出版信息

Top Curr Chem (Cham). 2024 May 19;382(2):19. doi: 10.1007/s41061-024-00466-9.

DOI:10.1007/s41061-024-00466-9
PMID:38762848
Abstract

Graphdiyne (GDY) is a new variant of nano-carbon material with excellent chemical, physical and electronic properties. It has attracted wide attention from researchers and industrialists for its extensive role in the fields of optics, electronics, bio-medics and energy. The unique arrangement of sp-sp carbon atoms, linear acetylenic linkages, uniform pores and highly conjugated structure offer numerous potentials for further exploration of GDY materials. However, since the material is at its infancy, not much understanding is available regarding its properties, growth mechanism and future applications. Therefore, in this review, readers are guided through a brief discussion on GDY's properties, different synthesis procedures with a special focus on surface functionalization and a list of applications for GDY. The review also critically analyses the advantages and disadvantages of each synthesis route and emphasizes the future scope of the material.

摘要

二维炔烃(GDY)是一种新型纳米碳材料,具有优异的化学、物理和电子性能。由于其在光学、电子、生物医学和能源等领域的广泛作用,引起了研究人员和工业界的广泛关注。其独特的 sp-sp 碳原子排列、线性炔键、均匀的孔和高度共轭的结构为进一步探索 GDY 材料提供了众多潜力。然而,由于该材料还处于起步阶段,对于其性质、生长机制和未来应用的了解还很有限。因此,在这篇综述中,我们简要讨论了 GDY 的性质、不同的合成方法,特别关注了表面功能化,并列出了 GDY 的一些应用。该综述还批判性地分析了每种合成路线的优缺点,并强调了该材料的未来发展方向。

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本文引用的文献

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Cucurbit[6]uril Hyperpolarized Chemical Exchange Saturation Transfer Pulse Sequence Parameter Optimization and Detectability Limit Assessment at 3.0T.3.0T下葫芦[6]脲超极化化学交换饱和转移脉冲序列参数优化及可检测性极限评估
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Promoting CO electroreduction to CO by a graphdiyne-stabilized Au nanoparticle catalyst.通过石墨炔稳定的金纳米颗粒催化剂促进一氧化碳电还原为一氧化碳。
Dalton Trans. 2023 Dec 19;53(1):245-250. doi: 10.1039/d3dt03432a.
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State, synthesis, perspective applications, and challenges of Graphdiyne and its analogues: A review of recent research.
石墨炔及其类似物的现状、合成、潜在应用和挑战:近期研究综述
Adv Colloid Interface Sci. 2023 Sep;319:102969. doi: 10.1016/j.cis.2023.102969. Epub 2023 Jul 27.
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Two-Dimensional Carbon Graphdiyne: Advances in Fundamental and Application Research.二维碳石墨炔:基础与应用研究进展
ACS Nano. 2023 Aug 8;17(15):14309-14346. doi: 10.1021/acsnano.3c03849. Epub 2023 Jul 20.
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Graphdiyne and its Composites for Lithium-Ion and Hydrogen Storage.用于锂离子存储和氢存储的石墨炔及其复合材料。
Chemistry. 2023 Sep 21;29(53):e202301722. doi: 10.1002/chem.202301722. Epub 2023 Aug 14.
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Hemocompatible Functionalized Hydrogen Substituted Graphdiyne Based Highly Durable Biosensor for Liver Cancer Detection.基于氢取代的石墨炔的血液相容性功能化的高耐用生物传感器,用于肝癌检测。
ACS Appl Bio Mater. 2023 Jun 19;6(6):2257-2265. doi: 10.1021/acsabm.3c00116. Epub 2023 May 17.
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Graphynes and Graphdiynes for Energy Storage and Catalytic Utilization: Theoretical Insights into Recent Advances.用于能量存储和催化利用的石墨炔和石墨二炔:对近期进展的理论见解
Chem Rev. 2023 Apr 26;123(8):4795-4854. doi: 10.1021/acs.chemrev.2c00729. Epub 2023 Mar 15.
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Understanding the performance of graphdiyne membrane for the separation of nitrate ions from aqueous solution at the atomistic scale.在原子尺度上理解石墨炔膜从水溶液中分离硝酸根离子的性能。
J Mol Graph Model. 2023 Jan;118:108337. doi: 10.1016/j.jmgm.2022.108337. Epub 2022 Sep 23.
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Single-Atom Catalysts Supported on the Graphene/Graphdiyne Heterostructure for Effective CO Electroreduction.负载于石墨烯/石墨炔异质结构上的单原子催化剂用于高效CO电还原
Inorg Chem. 2022 Aug 1;61(30):12012-12022. doi: 10.1021/acs.inorgchem.2c02020. Epub 2022 Jul 21.
10
Graphdiyne Oxide Quantum Dots: The Enhancement of Peroxidase-like Activity and Their Applications in Sensing HO and Cysteine.氧化石墨炔量子点:过氧化物酶样活性的增强及其在检测 HO 和半胱氨酸中的应用。
ACS Appl Bio Mater. 2022 Jul 18;5(7):3418-3427. doi: 10.1021/acsabm.2c00361. Epub 2022 Jun 15.