Li Mian, Fan Qi, Gao Lin, Liang Kun, Huang Qing
Zhejiang Key Laboratory of Data-Driven High-Safety Energy Materials and Applications, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China.
Qianwan Institute of CNiTECH, Ningbo, Zhejiang, 315336, China.
Adv Mater. 2024 Sep;36(37):e2312918. doi: 10.1002/adma.202312918. Epub 2024 Jun 12.
The intercalation of layered materials offers a flexible approach for tailoring their structures and generating unexpected properties. This review provides perspectives on the chemical intercalation of layered materials, including graphite/graphene, transition metal dichalcogenides, MXenes, and some particular materials. The characteristics of the different intercalation methods and their chemical mechanisms are discussed. The influence of intercalation on the structural changes of the host materials and the structural change how to affect the intrinsic properties of the intercalation compounds are discussed. Furthermore, a perspective on the applications of intercalation compounds in fields such as energy conversion and storage, catalysis, smart devices, biomedical applications, and environmental remediation is provided. Finally, brief insights into the challenges and future opportunities for the chemical intercalation of layered materials are provided.
层状材料的插层为定制其结构和产生意想不到的性能提供了一种灵活的方法。本综述提供了关于层状材料化学插层的观点，包括石墨/石墨烯、过渡金属二硫属化物、MXenes以及一些特殊材料。讨论了不同插层方法的特点及其化学机理。探讨了插层对主体材料结构变化的影响以及结构变化如何影响插层化合物的固有性能。此外，还提供了关于插层化合物在能量转换与存储、催化、智能设备、生物医学应用和环境修复等领域应用的观点。最后，简要介绍了层状材料化学插层面临的挑战和未来机遇。
