NHC-铜三配位络合物作为一种有前景的用于能量和电子转移反应的光催化剂。
NHC-Cu Three-Coordinate Complex as a Promising Photocatalyst for Energy and Electron Transfer Reactions.
作者信息
Grudzień Krzysztof, Szeptuch Zuzanna, Kubiszewski Hubert, Chaładaj Wojciech, Rybicka-Jasińska Katarzyna
机构信息
Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, Warsaw 01-224, Poland.
Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, Warsaw 00-664, Poland.
出版信息
J Org Chem. 2024 Jun 21;89(12):8546-8550. doi: 10.1021/acs.joc.4c00450. Epub 2024 Jun 3.
Herein, we describe a simple three-coordinate complex of Cu(I) with an NHC and 1,10-phenanthroline ligands as an effective photocatalyst for energy (e.g., olefin / isomerization) and electron transfer (e.g., aryl halide dehalogenation) reactions under blue-light irradiation. This complex can be obtained in a one-pot procedure starting from commercially available reagents and green solvents (EtOH, water). We hereby present a study of its activity and mechanistic insight into its mode of operation.
在此，我们描述了一种简单的铜（I）三配位配合物，它含有一个N-杂环卡宾（NHC）和1,10-菲咯啉配体，作为一种有效的光催化剂，可在蓝光照射下用于能量反应（如烯烃异构化）和电子转移反应（如芳基卤脱卤反应）。该配合物可通过一锅法从市售试剂和绿色溶剂（乙醇、水）制得。我们在此展示了对其活性的研究以及对其作用模式的机理洞察。
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