• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

NHC-铜三配位络合物作为一种有前景的用于能量和电子转移反应的光催化剂。

NHC-Cu Three-Coordinate Complex as a Promising Photocatalyst for Energy and Electron Transfer Reactions.

作者信息

Grudzień Krzysztof, Szeptuch Zuzanna, Kubiszewski Hubert, Chaładaj Wojciech, Rybicka-Jasińska Katarzyna

机构信息

Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, Warsaw 01-224, Poland.

Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, Warsaw 00-664, Poland.

出版信息

J Org Chem. 2024 Jun 21;89(12):8546-8550. doi: 10.1021/acs.joc.4c00450. Epub 2024 Jun 3.

DOI:10.1021/acs.joc.4c00450
PMID:38830237
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11197101/
Abstract

Herein, we describe a simple three-coordinate complex of Cu(I) with an NHC and 1,10-phenanthroline ligands as an effective photocatalyst for energy (e.g., olefin / isomerization) and electron transfer (e.g., aryl halide dehalogenation) reactions under blue-light irradiation. This complex can be obtained in a one-pot procedure starting from commercially available reagents and green solvents (EtOH, water). We hereby present a study of its activity and mechanistic insight into its mode of operation.

摘要

在此，我们描述了一种简单的铜（I）三配位配合物，它含有一个N-杂环卡宾（NHC）和1,10-菲咯啉配体，作为一种有效的光催化剂，可在蓝光照射下用于能量反应（如烯烃异构化）和电子转移反应（如芳基卤脱卤反应）。该配合物可通过一锅法从市售试剂和绿色溶剂（乙醇、水）制得。我们在此展示了对其活性的研究以及对其作用模式的机理洞察。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8623/11197101/9fe87817a340/jo4c00450_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8623/11197101/c07cdc33b838/jo4c00450_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8623/11197101/7804adfb90f8/jo4c00450_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8623/11197101/a74bdafdfd25/jo4c00450_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8623/11197101/0376fffe5c76/jo4c00450_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8623/11197101/9fe87817a340/jo4c00450_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8623/11197101/c07cdc33b838/jo4c00450_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8623/11197101/7804adfb90f8/jo4c00450_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8623/11197101/a74bdafdfd25/jo4c00450_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8623/11197101/0376fffe5c76/jo4c00450_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8623/11197101/9fe87817a340/jo4c00450_0005.jpg

相似文献

1
NHC-Cu Three-Coordinate Complex as a Promising Photocatalyst for Energy and Electron Transfer Reactions.NHC-铜三配位络合物作为一种有前景的用于能量和电子转移反应的光催化剂。
J Org Chem. 2024 Jun 21;89(12):8546-8550. doi: 10.1021/acs.joc.4c00450. Epub 2024 Jun 3.
2
Visible Light Mediated Photoredox Catalytic Arylation Reactions.可见光介导的光氧化还原催化芳基化反应。
Acc Chem Res. 2016 Aug 16;49(8):1566-77. doi: 10.1021/acs.accounts.6b00229. Epub 2016 Aug 2.
3
(NHC)Ni(II)-Directed Insertions and Higher Substituted Olefin Synthesis from Simple Olefins.（NHC）镍（II）指导的插入反应和简单烯烃的高取代烯烃合成。
Acc Chem Res. 2023 May 2;56(9):1070-1086. doi: 10.1021/acs.accounts.3c00035. Epub 2023 Apr 10.
4
Photo-induced energy transfer relay of N-heterocyclic carbene catalysis: an asymmetric α-fluorination/isomerization cascade.N-杂环卡宾催化的光诱导能量转移接力：一种不对称α-氟化/异构化串联反应
Chem Commun (Camb). 2021 Jan 26;57(6):729-732. doi: 10.1039/d0cc07264h.
5
Low-Coordinate NHC-Cobalt(0)-Olefin Complexes: Synthesis, Structure, and Their Reactions with Hydrosilanes.低配位NHC-钴（0）-烯烃配合物：合成、结构及其与硅烷的反应
Inorg Chem. 2017 Sep 5;56(17):10775-10784. doi: 10.1021/acs.inorgchem.7b01763. Epub 2017 Aug 21.
6
Syntheses, structural analyses and redox kinetics of four-coordinate [CuL2]2+ and five-coordinate [CuL2(solvent)]2+ complexes (L = 6,6'-dimethyl-2,2'-bipyridine or 2,9-dimethyl-1,10-phenanthroline): completely gated reduction reaction of [Cu(dmp)2]2+ in nitromethane.四配位[CuL₂]²⁺和五配位[CuL₂(溶剂)]²⁺配合物（L = 6,6'-二甲基-2,2'-联吡啶或2,9-二甲基-1,10-菲咯啉）的合成、结构分析及氧化还原动力学：[Cu(dmp)₂]²⁺在硝基甲烷中的完全门控还原反应
Dalton Trans. 2005 Mar 21(6):1066-78. doi: 10.1039/b415057k. Epub 2005 Feb 16.
7
Synthesis, Structures, and Photophysical Properties of Novel Four-Coordinate Cu(I) Complexes Supported by Chelating N-Heterocyclic Carbene Ligands.新型螯合氮杂环卡宾配体支持的四配位Cu(I)配合物的合成、结构及光物理性质
Front Chem. 2019 Jun 5;7:422. doi: 10.3389/fchem.2019.00422. eCollection 2019.
8
Internal and External Influences on Stability and Ligand Exchange Reactions in Bromido[3-ethyl-4-aryl-5-(2-methoxypyridin-5-yl)-1-propyl-1,3-dihydro-2-imidazol-2-ylidene]gold(I) Complexes.溴代[3-乙基-4-芳基-5-(2-甲氧基吡啶-5-基)-1-丙基-1,3-二氢-2-咪唑-2-亚基]金(I)配合物稳定性及配体交换反应的内部和外部影响因素
Inorg Chem. 2021 Jun 21;60(12):8546-8553. doi: 10.1021/acs.inorgchem.1c00325. Epub 2021 Jun 7.
9
Copper-Catalyzed Oxidative Carbon-Carbon and/or Carbon-Heteroatom Bond Formation with O or Internal Oxidants.铜催化的与氧或内氧化剂的碳-碳和/或碳-杂原子键的氧化形成反应。
Acc Chem Res. 2018 May 15;51(5):1092-1105. doi: 10.1021/acs.accounts.7b00611. Epub 2018 Apr 12.
10
Assemblies of Polyacrylonitrile-Derived Photoactive Polymers as Blue and Green Light Photo-Cocatalysts for Cu-Catalyzed ATRP in Water and Organic Solvents.聚丙烯腈衍生的光活性聚合物组装体作为水相和有机相中铜催化原子转移自由基聚合反应的蓝光和绿光光助催化剂
Front Chem. 2021 Aug 13;9:734076. doi: 10.3389/fchem.2021.734076. eCollection 2021.

引用本文的文献

1
Photoactive Neutral Three-Coordinate Cu(I) Complexes of Anionic N‑Heterocyclic Carbenes.阴离子型氮杂环卡宾的光活性中性三配位铜（I）配合物
JACS Au. 2025 Jun 9;5(6):2792-2801. doi: 10.1021/jacsau.5c00357. eCollection 2025 Jun 23.

本文引用的文献

1
Photoactive Copper Complexes: Properties and Applications.光活性铜配合物：性质与应用。
Chem Rev. 2022 Nov 23;122(22):16365-16609. doi: 10.1021/acs.chemrev.2c00033. Epub 2022 Nov 9.
2
Visible-Light Photocatalytic Reduction of Aryl Halides as a Source of Aryl Radicals.可见光催化卤代芳烃还原反应作为芳基自由基的来源。
Molecules. 2022 Aug 23;27(17):5364. doi: 10.3390/molecules27175364.
3
Visible-light-mediated copper photocatalysis for organic syntheses.用于有机合成的可见光介导的铜光催化
Beilstein J Org Chem. 2021 Oct 12;17:2520-2542. doi: 10.3762/bjoc.17.169. eCollection 2021.
4
Photocatalyzed E→Z Contra-thermodynamic Isomerization of Vinyl Boronates with Binaphthol.联萘酚光催化硼酸乙烯酯的E→Z反热力学异构化反应
Chemistry. 2021 Oct 7;27(56):13966-13970. doi: 10.1002/chem.202102536. Epub 2021 Aug 24.
5
Visible light photocatalysis in the late-stage functionalization of pharmaceutically relevant compounds.可见光照药物相关化合物的后期功能化中的光催化作用。
Chem Soc Rev. 2021 Jan 21;50(2):766-897. doi: 10.1039/d0cs00493f. Epub 2020 Dec 22.
6
Visible-Light Photocatalysis as an Enabling Technology for Drug Discovery: A Paradigm Shift for Chemical Reactivity.可见光光催化作为药物发现的使能技术：化学反应性的范式转变
ACS Med Chem Lett. 2020 Sep 21;11(11):2120-2130. doi: 10.1021/acsmedchemlett.0c00436. eCollection 2020 Nov 12.
7
Copper-Photocatalyzed -Thermodynamic Isomerization of Polarized Alkenes.铜光催化的极化烯烃的热力学异构化
Org Lett. 2020 Oct 2;22(19):7688-7693. doi: 10.1021/acs.orglett.0c02894. Epub 2020 Sep 18.
8
Deazaflavin reductive photocatalysis involves excited semiquinone radicals.去氮黄素还原光催化涉及激发的半醌自由基。
Nat Commun. 2020 Jun 23;11(1):3174. doi: 10.1038/s41467-020-16909-y.
9
Recent advances in photocatalyzed reactions using well-defined copper(I) complexes.使用结构明确的铜（I）配合物的光催化反应的最新进展。
Beilstein J Org Chem. 2020 Mar 23;16:451-481. doi: 10.3762/bjoc.16.42. eCollection 2020.
10
Copper's rapid ascent in visible-light photoredox catalysis.铜在可见光照光氧化还原催化中的迅速崛起。
Science. 2019 May 3;364(6439). doi: 10.1126/science.aav9713.