Cheng Jianjun, Zhu Yi, Zhan Fei, Wang Lei
Key Laboratory of Advanced Marine Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences Ningbo 315201 China.
Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University Beijing 100083 China
RSC Adv. 2024 Jun 11;14(26):18798-18806. doi: 10.1039/d4ra02843k. eCollection 2024 Jun 6.
Porous sandwich-like structures with surface roughness possess the capacity to sustain droplets, diminish the area of contact between solids and liquids, and augment heat conductivity, and thus delay ice formation when the temperature drops below the freezing point. The prevalence of this combination of surface roughness and a hollow sandwich structure has been observed in several organisms, such as lotus leaves, which have developed these features as a result of environmental adaptation. This study introduces a new design for a surface consisting of a micro-nano conical array and a foam structure with a gradient of pores. The primary components of this design were isocyanate and polyether. The hollow gradient sandwich structure was created by manipulating the water content to increase the porosity, resulting in the formation of a conical-pit morphology on the underside of the specimen. This configuration significantly decreased the amount of heat lost and the modulus of elasticity of the sample. Additionally, the micro-nano hydrophobic structure on the upper surface hindered the transmission of temperature and delayed the formation of ice. This concept, inspired by natural structures, has significant potential applications in the areas of anti-icing, energy conservation, and environmental preservation.
具有表面粗糙度的多孔三明治状结构能够支撑液滴,减小固体与液体之间的接触面积,并提高热导率,从而在温度降至冰点以下时延迟结冰。在几种生物体中都观察到了这种表面粗糙度与中空三明治结构相结合的情况,比如荷叶,它通过环境适应进化出了这些特征。本研究介绍了一种由微纳锥形阵列和具有孔隙梯度的泡沫结构组成的表面新设计。该设计的主要成分是异氰酸酯和聚醚。通过控制含水量以增加孔隙率来创建中空梯度三明治结构,从而在样品底部形成锥形凹坑形态。这种结构显著降低了样品的热损失量和弹性模量。此外,上表面的微纳疏水结构阻碍了温度传递并延迟了冰的形成。这一受自然结构启发的概念在防冰、节能和环境保护领域具有重要的潜在应用。