Mohammed Ameen Sameera Sh, Omer Khalid M
Department of Chemistry, College of Science, University of Zakho, 42002, Kurdistan Region, Iraq.
Department of Chemistry, College of Science, University of Sulaimani, Qlisan Street, Sulaymaniyah, 46002 Kurdistan Region, Iraq.
ACS Appl Mater Interfaces. 2024 Jun 26;16(25):31895-31921. doi: 10.1021/acsami.4c06931. Epub 2024 Jun 13.
Bimetallic-metal organic frameworks (BiM-MOFs) or bimetallic organic frameworks represent an innovative and promising class of porous materials, distinguished from traditional monometallic MOFs by their incorporation of two metal ions alongside organic linkers. BiM-MOFs, with their unique crystal structure, physicochemical properties, and composition, demonstrate distinct advantages in the realm of biochemical sensing applications, displaying improvements in optical properties, stability, selectivity, and sensitivity. This comprehensive review explores into recent advancements in leveraging BiM-MOFs for fluorescence-based biochemical sensing, providing insights into their design, synthesis, and practical applications in both chemical and biological sensing. Emphasizing fluorescence emission as a transduction mechanism, the review aims to guide researchers in maximizing the potential of BiM-MOFs across a broader spectrum of investigations. Furthermore, it explores prospective research directions and addresses challenges, offering valuable perspectives on the evolving landscape of fluorescence-based probes rooted in BiM-MOFs.
双金属金属有机框架材料（BiM-MOFs）或双金属有机框架代表了一类创新且有前景的多孔材料，与传统单金属MOFs的区别在于它们除了有机连接体之外还引入了两种金属离子。BiM-MOFs具有独特的晶体结构、物理化学性质和组成，在生化传感应用领域展现出明显优势，在光学性质、稳定性、选择性和灵敏度方面均有改善。这篇综述探讨了利用BiM-MOFs进行基于荧光的生化传感的最新进展，深入了解其在化学和生物传感中的设计、合成及实际应用。该综述强调荧光发射作为一种转导机制，旨在指导研究人员在更广泛的研究范围内最大限度地发挥BiM-MOFs的潜力。此外，它还探索了未来的研究方向并应对挑战，为基于BiM-MOFs的荧光探针的不断发展提供了有价值的观点。
