Singh Sukriti, García-Page Ana, Noky Jonathan, Roychowdhury Subhajit, Vergniory Maia G, Borrmann Horst, Klauss Hans-Henning, Felser Claudia, Shekhar Chandra
Max Planck Institute for Chemical Physics of Solids, 01187, Dresden, Germany.
Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Bhopal, 462066, India.
Adv Sci (Weinh). 2024 Aug;11(31):e2404495. doi: 10.1002/advs.202404495. Epub 2024 Jun 18.
Heusler compounds belong to a large family of materials and exhibit numerous physical phenomena with promising applications, particularly ferromagnetic Weyl semimetals for their use in spintronics and memory devices. Here, anomalous Hall transport is reported in the room-temperature ferromagnets NiMnSb (half-metal with a Curie temperature (T) of 660 K) and PtMnSb (pseudo half-metal with a T of 560 K). They exhibit 4 µ/f.u. magnetic moments and non-trivial topological states. Moreover, NiMnSb and PtMnSb are the first half-Heusler ferromagnets to be reported as Weyl semimetals, and they exhibit anomalous Hall conductivity (AHC) due to the extended tail of the Berry curvature in these systems. The experimentally measured AHC values at 2 K are 1.8 × 10 Ωcm for NiMnSb and 2.2 × 10 Ω cm for PtMnSb. The comparatively large value between them can be explained in terms of the spin-orbit coupling strength. The combined approach of using ab initio calculations and a simple model shows that the Weyl nodes located far from the Fermi energy act as the driving mechanism for the intrinsic AHC. This contribution of topological features at higher energies can be generalized.
赫斯勒化合物属于一大类材料,展现出众多具有潜在应用前景的物理现象,特别是铁磁外尔半金属在自旋电子学和存储器件中的应用。在此,报道了室温铁磁体NiMnSb(居里温度(T)为660 K的半金属)和PtMnSb(T为560 K的准半金属)中的反常霍尔输运。它们表现出4 µ/f.u.的磁矩和非平凡拓扑态。此外,NiMnSb和PtMnSb是首个被报道为外尔半金属的半赫斯勒铁磁体,并且由于这些系统中贝里曲率的扩展尾部,它们表现出反常霍尔电导率(AHC)。在2 K时,NiMnSb的实验测量AHC值为1.8×10Ωcm,PtMnSb的为2.2×10Ωcm。它们之间相对较大的值可以用自旋轨道耦合强度来解释。使用从头算计算和一个简单模型的联合方法表明,远离费米能的外尔节点是本征AHC的驱动机制。高能拓扑特征的这种贡献可以推广。