Xu Yaohui, Zhou Yang, Li Yuting, Hao Yechen, Wu Pingkeng, Ding Zhao
Laboratory for Functional Materials, School of New Energy Materials and Chemistry, Leshan Normal University, Leshan 614000, China.
Leshan West Silicon Materials Photovoltaic New Energy Industry Technology Research Institute, Leshan 614000, China.
Molecules. 2024 May 23;29(11):2451. doi: 10.3390/molecules29112451.
Magnesium-based hydrogen storage materials have garnered significant attention due to their high hydrogen storage capacity, abundance, and low cost. However, the slow kinetics and high desorption temperature of magnesium hydride hinder its practical application. Various preparation methods have been developed to improve the hydrogen storage properties of magnesium-based materials. This review comprehensively summarizes the recent advances in the preparation methods of magnesium-based hydrogen storage materials, including mechanical ball milling, methanol-wrapped chemical vapor deposition, plasma-assisted ball milling, organic ligand-assisted synthesis, and other emerging methods. The principles, processes, key parameters, and modification strategies of each method are discussed in detail, along with representative research cases. Furthermore, the advantages and disadvantages of different preparation methods are compared and evaluated, and their influence on hydrogen storage properties is analyzed. The practical application potential of these methods is also assessed, considering factors such as hydrogen storage performance, scalability, and cost-effectiveness. Finally, the existing challenges and future research directions in this field are outlined, emphasizing the need for further development of high-performance and cost-effective magnesium-based hydrogen storage materials for clean energy applications. This review provides valuable insights and references for researchers working on the development of advanced magnesium-based hydrogen storage technologies.
镁基储氢材料因其高储氢容量、丰富性和低成本而备受关注。然而,氢化镁缓慢的动力学和高脱附温度阻碍了其实际应用。人们已经开发了各种制备方法来改善镁基材料的储氢性能。本文综述全面总结了镁基储氢材料制备方法的最新进展,包括机械球磨、甲醇包覆化学气相沉积、等离子体辅助球磨、有机配体辅助合成以及其他新兴方法。详细讨论了每种方法的原理、过程、关键参数和改性策略,并列举了代表性研究案例。此外,比较和评估了不同制备方法的优缺点,并分析了它们对储氢性能的影响。还考虑了储氢性能、可扩展性和成本效益等因素,评估了这些方法的实际应用潜力。最后,概述了该领域目前存在的挑战和未来的研究方向,强调了为清洁能源应用进一步开发高性能、低成本镁基储氢材料的必要性。本文综述为致力于先进镁基储氢技术开发的研究人员提供了有价值的见解和参考。