A critical review on the use of flue gas desulfurization gypsum to ameliorate saline-alkali soils and its prospect for reducing carbon emissions.

Flue gas desulfurization gypsum (FGDG), a solid waste produced during sulfur removal in coal-fired power plants, has applications in saline-alkali soil amelioration due to its function of calcium‑sodium ion exchange. Existing research has focused on the use of gypsum to improve saline-alkali soils in non-coastal areas. However, coastal areas are not only extensively salinized, but an important source of methane, and surprisingly, FGDG may assist to decrease methane formation mainly by the action of sulfate radical. This is the first critical review to systematically discuss the effects of FGDG on both saline-alkali soil improvement and carbon emission control in tidal flats, including application status, amendment principles, environmental risks and methane emission control. After adding FGDG, soil salinization degree was weakened via adjusting soil structure, pH, exchangeable sodium percentage and electric conductivity, introduction of nutrients also promotes crop growth. The optimal FGDG dosage in tidal flats seems to be higher (>2 %) than that in non-coastal areas (<1 %). Its environmental risks regarding heavy metals and eutrophication are evaluated safe. In tidal areas, more methane is produced in hot seasons and ebb tides. Plants and invertebrates also promote methane release. FGDG controls methane production by promoting the activity of sulfate-reducing bacteria and inhibiting methanogens. Considering methane flux levels and seawater erosion, FGDG use in low tidal beach needs more research, while that in high and middle tidal beach is recommended. This review will expand applications and appropriate use of FGDG for reducing carbon emission and improving ecological services in coastal areas.